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Volume 12 (1866) (428 pages)

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Page: of 428

50 Ghe Hining
patter
wil Scientific Presa.
GConmmaninations.
In THis DerantNeNnT we invite the FREE Discussion of all
roper subjecta—correspondents alone being responsible for
he ideas and theories they advance.
[Written for the Mining and Scientific Press.)
BISULPHIDE OF OARBON.
{BY DR. LANSZWEERT.
Having lately been severely victimized by
the use of this deleterious and very explosive
compound, it may be proper for me to place the
public on its guard against a careless use of
tha sama; and having, moreover, noticed an
advertisement in your journal that a gentleman of this city, offers to the public a new
roasting furnace, by the use of which “all the
sulphur [evolved in the process of roasting
sulphurets] is saved; by being converted into
hisalphide of carhov, which is a valuable product, and will pay nearly all expenses,” I have
thought it might not ba out of place to give,
through your columns, a few facts with regard
to the manufacture, usa, and nature of this singular substanca. I think the geentleman above
alluded to must be mistaken, both with regard
to the real nature of tbe process of its manufacture, as well as in regard to its commercial
value. He certainly canuot convert “ all the
sulphur” contained in the sulphurets “ into biaulpbide of carbon;” neither is it possible
for the bisulphide so produced to “ pay nearly
all expenses,” at its present nominal value of
about five ceuts per pound, at which price it is
now offered to the trade. ‘The foilowing notes
on tha mavufacture, apparatus used, rectification, properties and industrial application of
this agent, may be ivteresting to your readers :
Bisulphide of carbon was discovered in 1796
by Lampadiua, and is expressed by the formula
CS?. For a long time this subject was known
only as a laboratory product. Within the past
fifteen years the process of its manufacture bas
been very much improved, and many iudustrial
applications have been devised for its use ;
while to meet the increased demand, it is now
prepared on a very large scale.
In 1850, M. Macquart, of Bouu, prepared
hisulphide of carbon in large quantities. In
1840, the kilogramme (over 2 pounds) was
sold in Paris at from 50 to 60 franes (ten to
twelve dollars) ; but in 1850, M. Deis aold it
at 8 francs, and since 1856 he has manufactured
500 kilogrammes daily, aud now sells it at
50 centimes (9 cents) the kilosramme. Bisulphide of carbon can be produced by the
direct combination of sulphur and carbon ata
high temperature ; also by the decomposition of
acertain number of organie compounds. In
heating simply a mixture of sulphur and carhon, there isno combination, as the sulphur
volatilizes before it has attained the temperature uccessary to tbe action; but when charcoal is heated to red heat, and the vapor of sulphur ia passed over this incandescent mass, the
carbou burns iu this vapor, producing bisulphide of carbon.
The earliest apparatus for the preparation of
this compound consisted of a porcelain tube
filled with fragmeuts of charcoal,and placed in
an inclined position in the center of a laboratory furuace. The upper end of tbis tuba
was closed by a stopper of clay and chalk, and
the lower end was connected by a bended glass
tube, with a beétle partly filled with watar.
Whan the charcoal was made red hot, the
stopper was taken out of the tube, and a piece.
of sulphur inserted; the sulphur, so placed,
melted and run into the tube, where it came in
contact with the red coal, was volatilized and
combined with it, producing bisulphide of carbon, which, in a state of vapor, is condensed
upon the water, aud settles to the bottom by
its specific gravity. This was the imperfect
laboratory process employed for its early manufacture, which was ona small scale ouly. Aa
already stated, this manufacture is now conducted on a very large scale, and the principle
of tha apparatus used is always the same, viz.,
that sulphur in vapor is always passed through
coke or charcoal brought to a bright red heat,
then condeusing tbe vapors of bisulphide cf
carbon as rapidly and completély as possibfe.
The first improvement made for this preparation was the use of a large tubulated earthen
retort to heat the coal. A tube of hard glass
or porcelain was put through tha tubulatura of
the retort, which was sn covstructed as to
reach nearly to its bottom, for the introduction
of aulphur. ‘The ueck of the retort was adapted
to a condenser cooled with a stream of water,
and communicating with a receiver, as already
described. With this apparatus large quantitics were obtainable. ‘he various kiuds of
apparatus now in use for the industrial manufacture of bisulphide of carboo ara actually
coustructed according to the same principle,
and differ only in the form of the retort, the
way of introducing the sulphur, and the different combinations of the condenser. It is impossiblé, without drawings, to give av intelligible description of tbe details of these various
kinda of apparatus; still I will endeavor to
give one or two of their most characteristic
details.
M. Peroncel, who has introduced the manufacture of this substance on @ very large scale,
heats the coke ina large cast-iron cylinder,
2 metres (about 3914 inches) high by 30 centimetres in diameter, placed vertically in the
furnace. he tube for the introduction of sul-phur is near the bottom of this cylinder. The
uppar part of the cylinder is connected with an
earthen jar, in whicb most of the bisulphide
is condensed, and trom which itruns into a
closed vessel placed under the jar; the noncondensed vapors are conducted by a tube
fitted to tha upper part of the eartben jar into
a refrigerating coil, where they arc condensed.
The coil is in connection with a close recciver.
This apparatus can produce nearly 100 kilogrammes of bisulpbide daily. The cast-iron
cylinder is very quickly attacked and destroyed
by the sulphurous vapor—it will scldom last
longer than a week. ‘Ihe use of fire-clay cylinders, tha same as those employed by the gas
manufacturers, may be considered an importaut
progress in the improvement of this mavufacture.
M. Gerard, of Grenelle, usea cast-iron cylinders two metres high, of an elliptic section (diamater 1.40 metre). hey are filled witb coke,
and the sulphur is introduced by means of an
inclined tube passing through the side of the
furnace, and reachiig uear the bottom of the
cylinders. ‘I'he sulphur vapor is thus obliged
to pass through the whole of the red heated
coke. Tbe vapors of bisulphide thus obtaioed,
ara first conducted to a receiver, where the
largest quantity is condensed ; that which does
not condense, passes to a refiigerator, conipoaed
of three large metallic cylinders, placed one
above the other, and connecting with each other
by tubes. ‘The whole is surrounded by cold
watcr. The vapors first pass into the lower
cylinder, where immediately a large quautity
condenses, the halance rising into the upper
ones, run from there in the lower, from which
by a tube they ara received in a close vessel.
This apparatus furuishes, in tweuty-four
hours, 200 litres (50 gallons) of impure bisulphide of carbon, weighing 248 kilogramnies,
ata cost of 41 kilograinmes of coke, and 230
kilograinmes of sulphur. Loss about five per
cent. of the crude materials employed.
Galy, Cazalat, and Huillard have patented,
in England, a large cylindric oven, divided
horizontally into two parts by a fire-clay grate.
This is denominated a calorifere, as being the
principal source of heat. The upper part of
the oven is vaulted, and supports a low, vertical chimvey, which can be closed partectly by
adaniper. Around this chimney is a circular
trough or reservoir, containiug the sulphur
which is kept liquid by the waste heat of the
chimney. From this, by way of a faucet, sulphur is run ag may be desired. At the bottom
of the lower part of the oven an opening is
inade sideways, to couuect the tube couducting
the vapors to the condensers. ‘Tha coke is
lighted iv the lower part, which is gradually’
teplaced when burnt out. The combustion is
coutihucd until the whole interior of the oveu
is at cherry-red. All the apertures are then
closed, and according, as described above, the
sulphur is run into the oven ; the melted sulphur
dripping on the fire-clay grate is instantaneously
reduced to vapors, and passed through the redheated coke; tbe vapors of bisulphide of carbon thus obtained pass to the condensers,
where they liquify.
{To be Continued.)
Growrs or Cutcaco.—By an estimate made
near the close of last year, it is calculated that
during 1865 nine thousand buildings were put
up in -Chicago. Six of them cost $100,000
each; forty others cost $30,000 each; and
eight hundred were worth over $1,000 each,
The total amount of capital employed during
the year was six million dollars. ‘The uumber
of new churches was seven ; schools, two, and
public halls, four.
Pirno.e has now thirty producing wells,
sixtecn that have produced, but are now out of
order. The daily yield, is 8,603 barrcls, or
six barrela per minute. At $6 per barrel, the
present price of oil, it amounts to $51,648.
The sum of $12,000 pays all the expenses,
being & profit of $49,618 every twenty-four
ours.
“Taree thousand of the finest poems iu the
English language” aro being collected, aod
will be published in ove volume, in London,
for Christmas.
Tue Viceroy of Egypt’s astronomer has discovered, by a course of astronomical calculations, that the great pyramids were built about
3,300 B. C. Bunsen thiuks it was 3,400.
{Written for the MinIng and Scientific Press.j
‘The Mines of Grass Valley and Nevada.
Tenet. Jan. 12,1866.
been, to use a Western phrase, “circulating,
aboot’ in the neighborhood of this place and
Grass Valley, nutil the present .anow-storm,
“and its” attendant “slush” and discomfort,
drove me in-doors, and I am no longer “ current.” ;
While thus unable to travel, it is probahlé
that I cannot be better employed than in jotting down some notes of what'I have seen and:
heard during the last two weeks, including, of
course, notices of the leading mines and mills
about Grass Valley and Nevada, some of
which, thougb I shall be able to-day to give
them but a passiug notice, are “ booked ” for a
second visit.
That I may be more fully understood, I will
premise that I begin with the notes taken
during a day spent among the mills and mines
located to tbe south and southeast of Grass
Valley, withiu a distanca of thrae miles. Tha
-first of thesc that I encountered, and ove of the
oldest establishments in the district, is the
“GOLD HILL MILL,”
‘Located one mile south of Grass Valley, and
superintended hy Mr. J. K. Edwards, a brother
of Mr. Hannibal Edwards, superintendent of
the Eurcka mines, Summersville, Tuolumne
county, and’a fine specimen of an experienced
and practical miner. ‘his is a 20-stamp mill,
driven by steam, the eogine used being of
the “double-acting, condensing, working-beam
pattern,” so much in vogne years ago, and
bearing the suggestive trade-mark of “ James
Watt & Co., Soho, England.” As I stood by
this fire-hreathing monster. my mind’ was carried hack to the days when, as a school-hoy, it
was.my duty to explain the mysterious diagrams
representing Watts’ noequaled invention, a
working model of which I had never seen until
that day, and as I watched the movement of
its complicated arrangement of rods and levers,
I could not wonder at tha superstitious dread
which the first engine must have inspired
among the unsettled miners of Northern and
Western England in the time of the great inventor.
The mill was employed at the time of my
visit in crushing quartz from the Loue ledge, of
wliich I shall speak more fully hereafter. <A
fine lot of quartz from the Illinoia lode was
also lying at hand, waiting its turn to be relieved of its precious charge.
Half a mile farther in the same dircetion
brought me to the
“ SEBASTOPOL MILL,”
Mr. Ben. McCauley, superintendent, which
was not running at thetime. This isa 12stamp custom mill, driven by steam, and
appears to be thoroughly and perfectly constructed in every part.
Half a mile southeast of the Sebastopol, on
Wolf Creek, is
“LARIMER’S MILL,”
Lately finished by Mr. Jno. W. Larimer, Sole
proprietor and manager. This is an 8-stamp
water mill, and is employed, like the two lastmentioned, in crushing custom-rock. Both
this mill and the Gold Hill at present use the
old syste of amalgamating in the batteries)
and on copper plates placed in slnices below ;
but Mr. L. contemplates a visit to the Bay io
a short time, for the purpose of cboosiug improved amalgamating apparatus, to be introduced into his mill.
‘A short: distance further to the southward
hrought me to the
“ILLINOIS MINE,”
The property of Messrs. Leech, Henderson,
and some others whose names I have forgotteu.
The coursa of the ledge is east and west, with
adip to the southward of 40 degrees. Its
thickness varies from aix inches to four feet,
the average thickuess thronghout being about
two feet. It is situated iu a granite formation,
aud consists of a light-colored, bluish gray
quartz, carrying large quautities of sulphurets,
. and pleutifully specked witb free gold, I was
‘informed that tha rock from this mine, crushed
Enirors Press:—Since my last, I have)
at the Gold Hill mill, had, thus far, averaged
fifty-two dollara per ton. ‘Tha workings have
reacbed a depth of 140 feet, and the word is,
the vein is “still improving.”
_ A short distance eastward from the-Ilinois,
ig q
“ PHE LONE JACK,”
Owned, in part, by Mr. C. T. Wheeler, of
Sacramento. I did not obtain any statistics in
regard to this mine, but was asaured by the
superintendent that it was “ doing well, which
was fully sustained by the appearanca of tha
quartz that was coming out of the mine.
About a mile from the Lone Jack, and
three miles southeast trom Grass Valley, is the
me STONE?
Owned by Messrs. Hurst, Samvel F. Curtis, of
the Savage mine, and Mr. Hunt, the present
superintendent. ‘Ibis mine haa been lately
opened on ground purchased of the Empire
company, and appears likely to soon rival the
most famous mines of this district in richness
and extent. he general course of tha lode is
north und south, with a dip to the eastward of
twenty-five degrees. Tbe ledge is represented
as having au average width ol threc fect, and I
am assured by Mr. Hunt that the average yield
has herctofore been $40 per ton. On meeting
Mr. H. the following evening, he told me that
they had that day taken out better quartz than
ever belore. He was sanguine that it would
pay $100 per ton. The proprietors are preparing to put up a 10-stamp mill, with a capacity
for twenty stamps, for whicb they expect the
engine now doing the hoisting and pumping
of the inine to furnish sufficient power, iu addition to its present work.
Returvivg, I stopped at the
“ HARTERY,”
Owned by Messrs. McLaughlin and Loutzenheiser, of Grass Valley, and Mr. J. 0. Keele, of
San Jose. As the superintendent was ahsent
at the time, I was unable to obtain all the information I desired. ‘The following facts I
learned fron Mr. Henderson, who is engaged
iu erecting the machinery for the hoisting
works, pump, aod mill, which the proprictors
have in process of erection. ‘The mine has
been explored to a depth of 140 feet, and extensive drifts have been run, disclosing a ledge
from one to two feet in thickness, and of such
richness, that the proprietors leel warranted iu
erecting an 8-stamp mill, which is now being
built.
On Monday [I left Grass Valley for this
place, and during the evening formed the aequaintance of Mr. S. P. Leeds, superintendent
of the Naw York and Grass Valley Mining
compavy, with whom, and Mr. Fenton, of Summit City, I visited the company’s mine and mill
at Gold Flat, three-fourths of a mile from the
city, and kuown as the
“ 8NEATI AND CLAY,”
From the names of its former owners, from
whom it was purchased by the New York and
Grass Valley Mining company. The vein is
situated in ‘@ primitive formation, the wall being
of syenite, or, as it has here heen called, granite, and is ol varying width, averaging probably
twenty inches. ‘The strike of the ledga is
north, twelve degrees east, and it dips to the
castward at av angle of twenty-three degrees.
‘The mine is opened to a depth of 350 feet, by
an incline, and is worked ou three different
levels, at depths of 212, 272 and 350 feet, on
all of which extensive drifts have been run,
and valuable ore taken out. ‘The quartz pays
from $18 to $25 per ton, and can certainly be
worked with probt in the iill, which stands
convenient to the mine, so that the ora is run
ov cars, from the top of the incline, direct to
the battcries. The mill has a capacity of twelve
stamps. Amalgamation of the gold in the batteries, by means of copper plates, is tbe principal mode of saving it, after which the heavier
sands are caught ov blankets and ground in
Chile mills, and, last of all, tbe sulphurets are
concentrated hy meana of shaking tables, and
saved,
After passing through and examining the
mine and mill, we proceéded to the
“ UNION MINE,”
Situated three and a half miles southeast of
Nevada, ina granite formation, the walls of
tha vein being of diorite, resembling in appearance the “Angcl Island Granite” of San
Francisco. The vein varies from a few inches
to four or five feet in thickness, averaging,
probably, two and ahalf or three feet. ‘he
course of the vein is nearly or quite north and
south, with a pitch to tha eastward of fortythree degrecs. licar the mine isa 5-stamp
mill, also the property of the company, in which
some of the ore is now being worked, paying,
Mr. Leeds informed me, an average ol about
thirty dollars per ton, Tha mine was formerly
worked throngh tunnels, driven in upon the
vein from the ravine to the southward, but Mr.
Leeds is opening it through a splendid incline,
which he calls his * Excelsior Shaft,” and it is
one he may well be proud of. Fiva feet by
fifteeu in the clear, and supported by timbers
sawn from the heart of the spruce, it furnisbes
@ convenient, roomy, and durable means of
access to all parts of the mina. ‘Thia ahaft has