Enter a name, company, place or keywords to search across this item. Then click "Search" (or hit Enter).
Collection: Books and Periodicals > Mining & Scientific Press
Volume 17 (1868) (428 pages)

Copy the Page Text to the Clipboard

Show the Page Image

Show the Image Page Text


More Information About this Image

Get a Citation for Page or Image - Copy to the Clipboard

Go to the Previous Page (or Left Arrow key)

Go to the Next Page (or Right Arrow key)
Page: of 428

18 The Mining and Scientific Press.
Volatility of Gold and Silver.
NUMBER THREE.
We resume the question of tho volatility
of gold, If gold be actually volatile to the
extent indicated by Mr. Napier’s experiments, it might be reasonably anticipated
that some gold would be fouud in the fluedust of the melting furnace, aud that some of
the precious metal might even fly ont into
sthe atmosphere at the top of the chimney.
In the experiments communicated to the
Chemical Society of London by Mr. Napier,
a digest of which was given in ourissuo of
Jnne 13th, analyses of deposits taken from
the top, middle, and hottom of a chimney
about 35 feet high were given,
A quantity of soot was also collected, as
it escaped into the atmosphere, ahout four
feet ahove the top of the chimney, which,
on examination, was found to contain three
per cent. of silver, with alsoa small portion
of gold. Soot deposited on a wall against
which the chimney stood, was fonnd to
contain 4.2 per cent. of silver, also some
gold. The most extraordinary feature in
these analyses is the presence of gold in
such large proportions; theamount being
at least douhle that which originally existed
in the alloy which was treated in the furnace, Mr. Napier hazards, in explanation
of this curious result, tho view that this
excess proportion of gold is carried off hy
vaporized metallic copper, owing to the
greater affinity of the latter for gold.
In Mr. Napier’s second series of experiments, . which are also referred toin onr issue of the 23d ult.,. the melted metal was
not, as in the preceding instance, covered
with charcoal ; but a number of bone-ash
cupels were kept floating upon the surface
of the molten metal, for the purpose of absorhing smal] qnantities of lead, which were
contained iu the silver operated upon,
Here the loss was of very serious amount,
while that of the silver was also quite alarming. These losses appear even more setious when we take into consideration the
fact that it is only that portion of the metallic suhstances which lodges ou the sides
of the chimney that has any chance of heing recovered.
In Napier’s experiments the alloys melted
contaiued gold as a minor constituent; in
the case of the silver coin, the gold formed
in this State aud Nevada; bnt only the
and inthat of the metal for parting, presumahly only one-third or one-fourth of the componnd, and yet in both cases gold found
its way into the flue-dust. With gold containing 96 per ceut. of the precious metal,
would there be asensible loss from like
causes? The correct answer to this question is, that the same kind of loss ocenrs ;
analyses and examinations made with the
deposits from the chimneys of numerous
melting honses in Anstralia have always
sbown the presence of gold in considerable
proportion. Similar results have not unfrequently been obtained from the hreaking
up or cleaning of melting establishments
twelve-hundredth part of the alloy, for evident reasons, little has been said ahout
it. Special care has been taken to keep
such facts out of the papers.
In melting the low grado product of
many of our mines, which often assays as
low as $14 per ounce the loss of gold must,
judging from the above experiments, be
much greater than when melting the product of those mines which yield very fine
gold. This isa matter deserving of the
most serious attention.
Moreover, the abundant uso of nitre and
corrosive Snblimate in toughening gold, as
is sometimes done, occasions violent action
in the melting pot; the use of these chemicals cansesan additional loss of gofd, presumably by mechanical projection, and the
question of tho cause of the loss of gold in
tho melter’s hand and of the state in which
it escapes into the chimney hay hecome far
more complex than in our early gold-melting days, when the alluvial gold of high
quality was the ouly material operated upon;
and when this, with the addition of alittlo . .
borax, was simply melted and ponred once
In some of tho larger melting houses iu
Melbourne, Australia, there is 1 considerable length of fino between the furnaceand
tho chimney-shaft, and in these flues, as
well as in the shaft itself, a deposit of dust
occurs. Jfrom fines of this description aud
from the shaft of oue of theso establishments tho accumulated dust was receutly
cleared out. ‘The dust from the flues afforded by assay for each pouud weight avoirdupois:
Grains.
Silver.. VLAS4
Gold.. 3 ell
White alloy of gold and SiIVCP.. cc cceceteeeeeeeeene 14,763
The dust from the shaft, similarly examined, afforded per pound avoirdupois :
Silver.
Gold.
White alloy of gold and silver 1. 4866
These results, which are reliable, must
speak for themselves; they represent the
average of what takes place in the ordinary
operations of an assaying establishment,
performing tho usual varieties of work.
if a sample of this fine-dust be taken in the
hand, aud closely inspected, neither gold
nor silver will he seen, and if it be re-.
washed down to a small hulk, the gold will
be almost, or altogether, invisible to the.
naked eye, or to the cye aided by a pocket
lens ; but if, after washing a sample, we
place the residne under a compound microscope with a magnifying power of abont)
ninety diameters, we shall theu observe,
lying among the stony particles, nnmerous
spherical globules, and groups of crystals
ot both gold and silver. The little golden
spheres are, many of them, exceedingly
brilliant, and perfect in form, and they may
be readily distinguished as varying from
the rich yellow of fine gold to the pale
greenish yellow of alloys coutaining mnch
silver, so that it can be certainly stated that
these minnte particles widely differ from
each other in fineness. If, again, a portion
of dust be removed from the flues of a muffle-stovo which has been for some timo iu
constant use, very similar results will be
also obtained. After washing this dust,
little amher-colored translucent spheres, apparently silicate of lead, may be observed
under the microscope, and interspersed
among these, countless metallic glohnles
tolerably nniform in size bnt varying in
color, and conseqnently in their proportions of gold and silver much as those in
the fiue-dust of the wind furnace vary.
Tf gold he cupelled with lead, but without silver, there is a notable loss of gold ;
as often as we repeat the operation on the
same piece of pure gold, so often we occasion a further loss of weight. Bnt iu the
cupellation of gold with silver and lead, as
conducted in the ordinary assay, there is a
palpable loss of silver, bunt no apparent loss
of gold; it appears as though the presence
of the more volatile silver shielded the gold
and prevented its loss. In reality the case is
very different from what it appears, for hoth
gold and silver are actually lost, hut as the
resulting cornet is never pnre gold, bnt always contains a residue of silver, so the real
loss of gold is covered and more than covered by the excess of silver which pertaius
to the cornet after all the operations of the
assay.
To make this quito clear, we venture to
give anexample. If 10 graimsof pure gold
are cupelled with 30 grains of silver, .and
100 grains of pure lead, we shall obtain a
cornet weighing a little over 10 grains—say
10.008, the excess of 8,000ths of a grain is
considered as silver left in the gold, and an
allowance for this surcharge, as it is called,
is made in the common assay. Bnt if we
now analyze the 10.008 grains of gold ohtained as onr result, we shall obtain more
than 8,000ths of a grain of silver—say 12,000ths ; in this case the extra 4,000ths of
of silver go to cover the loss of the same
weight of gold during the cupellation,
CONCLUSIONS.
From these several resnlts we learn that .
at very high temperatures gold is volatile ;
that gold melted at the temperature of our
common fnrnaces sniffers considerable loss;
that the lossis apparently angmented hy the
presence of other metals, especially by snch
as are of a volatile naturo. We learn, too,
that gold passes off in the assay muiile, and
that it may be recognized in, and recovered
from, the flue dust ; moreover, that it actualiy passes out of the chimney-top into
the atmosphere. How far in these several
instances it passes offin vapor, and how far
it is mechanically swept away in the dranght
as gold mist, if we may use sucha phrase,
has yet to be determined ; for, although the .
experiments of Napier are conclnsive as to
the facts hronght forward, the deductions
which he has made can scarcely be received
as final or conclusive.
<=
A Brivurant Invention ror Burypine,
Bureuars,—The carrying of weapons has
long been forhidden in France to persons
in civil life; bunt a brilliant Parisian invention has lately been made, which, while
conforming with the law, is a partial aid as
a means of defence against burglars and
other night robbers. It consists of a horn,
inserted in the end of a cane, which horn
contains an electric battery and a small
lamp with two powerful reflectors. The
intensity of this light temporarily blinds
any person at whom it is pointed. The.
lamp is kindled at will by pressing a small
knob at tho other end of the cane, which
kuob communicates with an electric wire.
Locomotives in Mining Tunnels.
Eprrors Press.—The ineclosed calculations and queries are sent with the reqnest
that they be published in the Miytne anp
Screntiric Press, for the purpose of obtaining the facts in regard to the feasibility
of rnnning engines in tunnels for mining
purposes at a reasonable degree of expense.
If that could be done, it would add much
to the valne of Sierra County; and of
course, to all places where gravel deposits
lie far back into the hills. The conditions
of the calenlations apply to all companies
just begining to operate in this immediate
locality; hut hefore they gct worked ont,
they will have to car at least a mile. If you
publish the communication, please make
such notice or comment in regard to it as
you may_see fit. The companies are all
anxions to know if engines can be used iu
carrying. Trnly yours, J. F. Coun.
The following are the calculations and
qneries above referred to:
Company A employs five carmen on a
main track tnnnel, 2,500 feet in length,
with an ontward descent of six inches per
hnndred feet, or abont twenty-eight feet
per mile, running at the rate of sixteen
trips each, on a shift, with loaded cars
weighing 3,000 pounds each. The cost of
that carrying for a year wonld be, for five
men by day and five by night, ten men
working, say 300 days each, at $324 per
day, $10,500.
If a locomotive could be used the cost
. per year would he—
Cost of locomotive and apparatus.
Ap IETESt and i rye
ue
Engineer..
amount of cost first year
Balance In favor of locomotiy. $3,150
Baltnee, sceond year. 6.450
third ‘a 6.450
fourth * 6,459
Saved In four years....:escseceneeee $22,800
Suppose two companies aro situated so
that the same locomotive could be used hy
both, and instead of performing tho work
of ten men per year, it could do the work
of twenty men, with the above conditions;
then the estimates would be the labor of
twenty carmen for 800 days each, at $34
per day, $21,000, Cost ot engine per year,
$7,050.
Balance in favor of engine first year
Balance ln favor of cnyine secottd 5¢
Balance In favor of engine thi year..
Balance jn fuyor of engine tourth year.
Amount saved in four years..-.----...0.005The importance of the following queries
are manifest and positive: Can an engine
be used in a tunuel threc and one-half teet
wide by tive feet high, with ample ventilation, so that the heat and steam will not iuterfere? What kind of fuel could he best
employed—coal, petroleum, oil, charcoal,
coke, or what? Cau the smoke be condensed or consumed, or a jet of steam be
employed to destroy its uoxious qnalities ?
How many empty cars, weighing 1,000
pounds each, conld a 40-cwt. engine draw
up a grade of forty feet per mile, at a maximum rate of five miles an hour? Have
locomotives ever beeu used in tunnels; and
if not, why not, where the operations are
extensive enough to justify the ontlay ?
Answers to any one or all of the above
queries, through the columns of the Press,
are respectfully solicited. Could engines
he used in caring, they would add untold
wealth to the State. There are large tracts
that would unquestionahly pay, if the caring cost, at the outside, sufficiently less
than hy ordinary means,
Table Rock, Sierra Co., June 28, 1868.
dl, dB, (Ce
In place of according to Mr. Colo’s inquiry the customary hrief observations
which only can he afforded by the limited
space at our disposal iu the column set
apart to Notices to Correspondents, we have
preferred to publish his letter in extenso,
deeming the inquiries of sufficient importauce. The subject matter of inquiry is not
one on which we can pass any opinion, so
far as personal experience is conderned.
We have, however, made some inqniries on
the subject, and one gentleman states that
iu South Wales, the iron ore, raised in such
immense quantities iu that district, is iu
several places drawn in cars through tunnels hy 2 small locomotive. This, he states,
has been the casofor many years, and is
given from his own positive knowledgo,
Coals, he states, as he has been informed,
have also heen withdrawn in a similar manner. He also states that rails, three feet
tion of an ordinary railroad of some length
jua hilly district_of North Wales, an account of which was recently published in
the Mrnine anp Screntiric Pruss. We
think, however, tho party allnded to, conenrs in the opinion, that a hight of five feet
wonld scarcely snflice to render the inconvenience of the waste steam from becoming
very troublesome and annoying, ‘To remedy this drawback, the gentleman named
suggests that for the purpose of ohtaining
tractive power, in place of employing a
locomotive, an endless rope might he nsed,
worked by a revolving drum, set in motion
by a stationary engine at the mouth of the
tunnel. The tunnels in England have been
worked in this way since the opening of the
Manchester and Liverpool Railway, in 1830,
one tunnel heing abonta mile and a half,
and another a mile in length.
Ross Browne's First Report.
We are indebted to Prof. W. P, Blake
for some advance sheets of J, Ross Browne’s
second and final report upon the ‘Mineral
Resonrees of the States and ‘Territories
west of the Rocky Monntaius.” The sheets
before ns comprise 176 pages, ‘The Professor writes us that at the date of mailing
the imperfect copy sent, the entire volume,
which contains 700 pages, was already ont
of the press, and in the hands of the binders, so that we onght to receive the balance
of the work soon. Upon tho first of the
pages before us, we find the following as
the heads of the various points to which
special attention is given in the report:
1. The origin of gold mining on the.Pacific Coast and present condition of that
iuterest, as tending to show the progress
of settlement and civilization.
2. Geological formation of the great
mineral belts and general characteristics of
the placer diggings and quartz lodes,
3. Different systems of mining, machinery used, processes of redncing the ores,
percentage of waste, and net profits.
4. Population engaged in wining, exelnsively and in-part, capital and labor employed, value of improvements, number of
mills and steam engines in operation, yield
of the mines, average of dividends and
losses. :
5. Proportion of agricultural and mineral landsin each district, quantity of woodland, facilities for obtaining fnel, numher
and extent. of streams, and water privileges,
6. Salt beds, deposits of soda and horax,
and all other valuable mineral deposits,
7. Alt.tude, character of climate, mode
and cost of living, cost of all kinds of material, cost of lahor, ete.
8. Population of the mining towns, number of hanks and banking institutions in
them, facilities for assaying, melting and
refining bulliou; charges upon the same
for transportation and insurance.
9. Communicatiou with the mines and
principal towns, postal and telegraphic
lines; stage routes ; cost of travel; probable benetits likely to resnlt from constrnetion of the Pacific railroad and its proposed
branches,
10, Necessity for assay offices and public
depositories ; what financial facilities may
tend to develop the country and euhance
its products,
11. Copies of local mining laws, and customs regulating the holding and working
of claims.
12. Number of ledges opened, numher
claimed, character of the soil in the mining
districts, and its adaptation to the support
of a large population.
The 176 pages Lefore us, after a few preliminary remarks, are entirely devoted to
the consideration of so much of the first
point enumerated as relates to California.
In presentiug the present condition of the
mining interest of this State, each county
is considered separately, and each of the
ptincipal mines in the several counties is
separately examined and reported npon.,
The report is evidoutly very claborate, and
we have no doubt it will fnrnish a large
amount of valuable information—far more
than will be considered commensnrate with
its cost. We shall speak more fully of it
. when wehave the eutire docnment before us.
six inches apayt, would amply suffice for. Since the above wasiu type, Mr. Browne
the purpose, or possihly even of narrower . has laid upon our table the report comgange; as railroads of that narrow gange . plete, but too late for further examination
have been fonnd well adapted for the forma-. this week,