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Volume 17 (1868) (428 pages)

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Page: of 428

The Mining and Scientific Press.
19
Hechanical,
The Durability of Materials.
NUMBER 1.
The durability of metals, like that of organized substanees, depends mainly on the
resistance they offer to a combination with
oxygen; and thns their deeay may also be
regarded as a slow combustion. Dnt their
durahility further depends on the character .
of the oxides formed on their surface. Iron
exposed to moisture will soon he coated with
rust, in the form of hydrated peroxides;
and as the exides do not adhere to the surface, ndditional flukes constantly form nnd .
fall away, until the whole mass is destroyed.
Wrought tron ina pure dry atmosphere
anffers, practically speaking, no deterioration in any Inpse of time. It is extremely
durable in distilled water free from air: but
it is slowly oxidized in n moist atmosphere,
nnd with fatal rapidity in air or water containing free aeids or other corrosive agents.
It is, however, efliciently protected from
knch agents by paint, which adheres to
elean iron with great tenacity. Itis alson
fuet, not hitherto satisfactorily acconnted
for, that oxidation is tea grent extent arrested by vihration’ The painting of
wrought-iron girders and roofs, more especially in tho neighborhood of smoky
towns, is a precaution of tho ntmost importance. Hvery eare shonld ho taken to
expose tho irou as freely as possihle to the
air, to leave no hollows where watcr can
collect, to avoid tho contact of damp earth,
nnd especially of vegetation, and to throw
tho material into the form of heavy bars
rather than thiu plates, Painting is more
economically performed, and more efiectual, when constantly attended to, than under the vicious practice of laying on three
or four eoats, and then leaving the work for
years, till the paintall pecls off, with a layer
of rust attached to it.
Tho Britannia Bridge furnishes a striking
Ulustration of the value of this system.
The maintenance had heen effected hy two
or three men, constantly on the work, who
attended to the slightest symptom of local
discoloration. As a consequence, the author
did not hesitate to express his firm belief,
that the total loss from rnst of the 10,540
tons of which the tubes consisted, did not
in twenty years amount toa single pound
weight.
Cast iron, when exposed to the action of
sea water, slowly decomposes the iron; being dissolved, leaving behind a graphite or
plumbago. ‘The action is, however, superficial, and very slow. It cau he preserved
by painting, where accessible for that purpose, or hy any protection which prevents
eontinual renewal of the surrounding medium, 2s when inelosed in brickwork or
masonry. In fresh water it suffers no such
deterioration, and under ordinary cireumstances its durability in a pure atmosphere
appears unlimited.
In the case of zine, although the bright
metal oxidizes even more rapidly than iron,
yet the oxide adheres witb such tenacity to
the metal tbat it affords an efficient proteetion against the continuation of the process.
To this property tho metal owes its great
durability, more especially as its oxide is
insoluble in water. In the presenee of any
solvent of the oxide, this metal is so speedUy destroyed as to be practically nseless,
unicss proteeted by paint. Tho destruction
of zine in smoky districts is, however,
principally due to galvanie action. A siinilar action produces the rusting away at the
base of iron railings, when fixed in stonework, as is usually the euse, by being run
in with lead. The contact of copper with
the irou plates of a vessel is also a source
of great danger; and there are numberless
other instances iu which the contact of metals of different conducting powers is equally
destruetive. In all such cases the use of
paint furnisbes, at any rate, a temporary
remedy.
It is difficult to over-estimate the value of
the introduction of the process of eoating
iron plates with vine, by simply eleaning
and immersing them in the molten metal. .
All that has been saidon the subject of zine
applies equally to galvanized iron, as it is
ealled. In oelear atmosphere its great dnrability, its stiffucss, its freedom from expansion, and its economy, are all qualities
of the highest value; while, on tho other
hand, witbout eonstant painting, itis wholly
unfitted for the atmosphere of smoky towns,
or manufactories, or even stations where it
is exposed to the fumes from locomotives.
Both the eorrosive and the galvanic actions,
which in such cases are so destructive, do
not cease witb the destruction of zinc, which
is soon nffected but eontinnes also to aet, .
with fatal effect, upon the iron itself, as
may he seen in many railway stations and
} and carbonic acid in moist air.
sheds near the manufacturing towns. Tho
corrosive tendency in zine and iron obliges
the use of less oxidizahle metals, copper
and lead. Lead slowly absorhes oxygen
Tt is acted
upon by certain waters, and is occasionally
ridWed with holes hy the larvn of an insect;
and its expansion and contraction requires
to Le allowed for in its use, Its ductility
render it a valuable material. Copper
might, however, in many instunees, be nsed
with great advantage in its stead.
The action of sen water on copper is so
importont that it was particularly alluded
to. The cbjcet in covering a vessel with
copper is solely to prevent the adhesion of
harnaeles and other molluscs. This property is not dne to the poisonous quality of
its salts, as is sometimes asserted, nor is
eopper used on aeconnt of its durable qualities; on tho contrary, its valne depends on
its slow destruction. The chloride of copper formed beneath the attachment of the
harnaclo being a soluble salt, the creature
no sooner effects a lodgeihent than it is at
onco set free by the solntiou of the salt;
while the salts which forms on zine or
iron being insolnhle, the plate is rather protected than otherwise hy the tenactons parasite. Hence the difficulty of devising an
eflicient paint for iron ships; for while, ou
the one hand, it must be slowly solnhle in
water to prevent this adhesion, it must, on
the other hand, he sufficiently insoluble to
he durahle. Ordinary oil paint is the most
efficient material for protecting either metals or wood from theefiects of moisture and
nir; but all oils, resins, and gums exposed
to air, and especially to the light of the snn,
oxidize and huru away with more or less
rapidity, leaving a powdery residue behind.
As a preservative of paint against tho heat
of the sun and light, attention was directed
to tho virtue of a coating of silicious sand,
dredged on the paiut while wet,
The durability of matter is a snbject of
the highest philosophieal interest. The
universal law on this planet appears to be
that no form shall he permanent. Neverceasing destruction and reconstruction are
characteristie, within the range of the atmosphere, of everything that exists, whether as regarded organie life orinorganie matter; and it is prohable that even the atmosphere itself is suhject to the same decree.
Excrnient Extry Wuerus, which may
be used witb water, as are grindstones, are
made by dissolving gum shellae in aleohol,
mixing the emery with it and pouting and
pressing in molds. Good wheels may also
be made hy a mixture of glue, dissolved,
and emery, treated in a similar manner.
Ordinary wheels are made hy covering the
periphery of a wooden disk, snitably secured to a mandrel, with folds of woolen or
eanton flannel, and covering the whole
with leather or strong cloth. Upon this is
placed a eoating of emery sceured by zine,
Tue town of Winehendon, Mass., elaims
to manufacture more wooden ware than any
otber town in the world. Two of the largest firms turn out $500,000 and $200,000
respectively, and the smaller establishments
of the place make the aggregate annnal
product of the wooden ware interest mount
up to over $1,000,000. In addition tothese
factories, Winchendon contains two cotton
mills, two bobbin mills, two machine shops,
and two sewing machine manufactories.
Stern is successfully alloyed with other
metals, improving its qualities for some
purposes. One five hundredth part of
silver adds immensely to the harduess of
steel and yet increases its tenacity. One
hundredth part of platinum, though not
forming so hard an alloy as the silver and
steel, gives a very great degree of toughness. Rhodium, palladium, iridium, and
osmium, make steel very hard, but tbeir
use, from their cost, is confiued mainly to
the experimental laboratory.
l Driaiep vs. Puxcerp Hoxrs.—A large
numher of specimens of steel plates were
recently tested at Chatham Dock-yard, to
determine the differenccin streugth between
steel plates with punched and drilled holes.
The advantage in teusile strain, gained when
the holes are drilled rather than puuched,
was calculated to be 22.5 per cent,
Durima the summer, twelve or fifteen
largo iron furnaces are to he erected in Lehigh Connty, Peunsylvania,
Sctentifie Miscellany.
Science in the Arts.
A somewhat remarkable instanco of the
vnluo of seience to tho arts is cxemplitied
in tho recent development of a new industry, under tho direction of Messrs. Maumend & Nagelet, of Paris. This is pronounecd one of tho most singular discoverics in the history of agricultnre. It has
long heen known that sheep draw a considcrahle quantity of potash from tho land
upon which they graze, much of which is
excreted from the skin with the perspiration
of tho animal; and it has been shown by
Chevreul that this peculiar potash compound, which is known as ‘‘snint,” forms
no less than one-third the weight! of raw
merino wool; while of ordinary wools it
constitutes ahout fiftecu per cent, of the
ficcce.
As this eomponnd is soluble in cold water,
+-it is easy for the wool manufacturer to produce a more or less eoncentrated solution
of the same, and from which tho potash
may be reeovered by an appropriate treatment. The process of this treatment constitutes tho new industry alluded to, and
which is now being introduced into the
principal woolen mannufactorics of France,
The plan adopted by Messrs. Maumené &
Ragelet is a very simple one, and is descrihed as follows:
They eyaporate the solutions which are
sent to them, until a perfectly dry and somewhat charred residue has been ohtained.
This is placed iu retorts and distilled, very
much in the same manner that coal is distilled at gas-works ; and the result is that,
while mueh gas is evolved, which can he
used for illuminating the factory, and much
ammonia is expelled, which ean he collected
and utilized in many ways, there remains a
residne, which chiefly eonsists of earhonates, sulphate, and chloride of potassium.
These three salts are separated by the usual
method, and then pass into commerce.
Curiously enough, they are remarkably free
from soda.
Some idea may he formed of the prospective magnitude of this new industry,
from the fact that there are nearly 50,000,000 fleeces washed annually in France,
which wonld yield, if all subjeeted to this
process, not less than $2,800,000!
Sheep fecding, it is well known, is very
exhuustive to the soil, The facts above developed make elear tho manner in which
this deterioration occurs, and points outthe
remedy. The potassic eonstituents so extensively drawn upon must be supplied ;
it is a duty the farmer owes to the soil,—the
neglect of it is but little short of a erime to
the community. The entire development of
the above series of facts affords a most practieal illustration of the valne of scienco in
the arts.
Passace or Hyprocen tHrovucnH Iron ar
4 Low Tremprrature.—Not long ago we
gave sone aecount of tbe transmissihility
of gases through cast irov at high temperatures. To-day we give an interesting experiment which shows that hydrogen will
pass through cast iron at the ordinary temperature. M. Cailletet took au iron flask
with a long (curved) neck, exhausted the
nir from it, and placed the mouth under
mercury. ‘he body of the flask was then
set iu a vessel of dilute sulphuric acid,
The outer surface was, of course, attacked
by the aeid and hydrogen evolved, some
of which passed into the interior of the
fiask, and, driving out the mercury, escaped
iu bubhles from tbe trough. There may
be more iu this experiment than M. Cailletct suspects. Hydrogen passes into metals with most remarkable facility, und Mr.
Graham believes is liquified with them.—
Mechunics’ Magazine.
Exgcrricity In Vacvo.—Mr. Alvergniat,
of Paris, has constructed anew apparatus
for proving that electricity cannot pass
throngh an absolute vacunm. ‘Two platinum wires areinserted into a tube so that
their free ends are within about au eighth;
of an inch of each other, ‘The «iy is then
exhausted from the tube ‘iy means of a
. mercurial column, nfter which the electric
. spark will not pass from one platinum wire
. to the other. ‘
A Sarcvnomerer,—M. Coret has recently
deviscd an instrument—a saturomcter—
which is intended to be affixed to steam
beilers which use salt water, to determine
the degree of saturation and at the same
time to reeord tho level of the water in the
boiler. Tho action of tho instrument depends on tho well-known principle that
when two different liquids, having the same
temperature and no chemical affinity, are
placed in an inverted syphon, their hights
in eaeh column, under the condition of
equilihrium, will be inversely as their densities. ‘Iwo glass tubes, communicating
with each other at the hottom, are placed
side hy side with a gradnated scale between
them. One tube is eonnected with the
feed-water, and the other with the water in
the hoilers ; so arranged that when the
eomparison is to be mado the connections
are cut off. It is said tho accuracy of this
apparatus permits a nearer approach to the
point of saturation than formerly, thus obviating the difliculties and loss of heat arising from an unnecessarily frequent “‘blowing off,” to remove the excess of saline
deposits from the hoiler.
To Exrcrro-Puars Parrr or orper F'1Brous Marertau.—A mode has been devised for depositing eopper, silver or gold,
hy the electric process, upon paper or any
other fibrous material. This is aceomplished by first rendering the paper a good
conductor of electricity, without coating it
with any material whieh will peel off. One
of the hest methods is to take a solution of
nitrate of silver, pour in liquid ammonia
till the precipitate formed at first is entirely dissolved again ; then place the paper,
silk, or muslin, for one or two hours in this
solution. After taking it out and drying
well, it is exposed to a current of hydrogen
gas, hy which operation the silver is reduced to a metallie state, and the material
becomes so good a conductor of electrieity
that it may be electro-plated witb copper,
silver or gold in the usual manner. Material prepared in this manner may be employed for various useful and ornamental
purposes,
Consvustion.—The perfect combustion of
one ton of antbracite eoal or of eoke, requires over 5,970 pounds of oxygen, derived from abont 340,000 eubie feet of air at
ordinary temperature, equivalent to a eolumn one foot square and over sixty-four
miles in length. This ealculation is based
upon the supposition thatall of the oxygen
of the air is made available, but in practice
it is found necessary to introduce twiee the
qnantity of air that by calculation would he
sufficient.
In the conversion of one part of solid
earbon into carbonie oxide, there are involved 2,473 heat units. Inthe eonversion
of the earbonie oxide thus obtained, into
carbonic acid, there are involved 5,607 heat
units, making 8,080 heat units in all, of
whieh the first or imperfeet eombustion
yiclded but thirty-one per eent. of the obtainable heat ; so that to limit the supply
of air so as to cause the exclusive production of carbonie oxide, would necessitate
the use of three times as much fuel as would
be required to do the same work were it
properly burned.
Gut Wirr.—The gilt wire employed in
making gold lace soon tarnishes. The surface of gold seldom being perfeetly eontinuous, sulphur gets at the metal beneath,
whether copper or silver, and the wire
quiekly blackens, To avoid this result,
M. Helouis proposes to insert a thin layer
of platinum between the copper and the
gold. Todo this, he drives a bar of copper into a ring of platinum strongly heated.
‘The eoutraction of the platinum on eooling
fixes it firmly to the eopper, and tbe wire
may be drawn without any risk of sepnrating the two metals. The gilding may be
done as usual. The eolor obtained is as
good as that of silver gilt wire, and, of
course, lasting, for sulphur will have no
effect, on tbe platinum.
In 1829, there wero but three miles of
railway track iu the United States; to-day.
there are not less than 38,500 miles. ‘The
railroad business of the Untan employs
ebout 500,000 men.