Enter a name, company, place or keywords to search across this item. Then click "Search" (or hit Enter).
Collection: Books and Periodicals > Mining & Scientific Press
Volume 18 (1869) (430 pages)

Copy the Page Text to the Clipboard

Show the Page Image

Show the Image Page Text


More Information About this Image

Get a Citation for Page or Image - Copy to the Clipboard

Go to the Previous Page (or Left Arrow key)

Go to the Next Page (or Right Arrow key)
Page: of 430

The Mining and Scientific Press.
Ww. B. MWER. A. T. DEWEY.
DEWEY & CoO., Publishers.
Orrice—No. 414 Clay street, between Sansome and Battery.
Writers should be cautious nbout addressing correspondence relating to the business or Interestsot a firm to an individual member thereof, wbose absence at the time might
causo dclay.
Terms of Subscription;
One copy, per annum, in advance.
One copy, six months, in advance
Carriers and gayFor sule by Newsdealers. 6@ :
Our Agents.
Our Feiexps can do mnch in aid of our paper and the
cause of practical knowledse and science, hy assisting our
Agents In their labors of canvassing, by lending their influence and encouraging favors. e shall send none but
‘worthy men.
Traveling Agents.
A. B. Bure, California, agent and correspondent.
Wx. H, Murray, California.
Tin _L. G. Yates, Callfornia.
8. H. Hernine. Californla and Nevada,
T. G. ANDERSON, Nevada.
Mesident Agents.
Waite Pixk District.—Alexander Bruckman, liamllton,
Nevida.
HeLena, Montana.—R. F. May.
Buack Haws, C, T.—Harper M. Orahond, H
CunteaL City, ©, T.--Méssrs. Richards & Cranc, of the
Citv Book Store, Main strect, will act as our agents.
GrorRGETOWN, ¢.T.—John A. Lafferty, Postmaster, {s onr
agentin this place.
SARTRE City, C. T.—Messrs. Woolworth & Moffat, arc our
agents for this place. 5
Guerenng, 0. T.—Mr. Robert Becrsls our authorized
agent for this place.
Omana, N. T.—Messrs. Barkalow & Brothers, are our
agents for thls place.
A. S. Hopkins, No. 70 J street, Sacramento.
Mr. A. C. nox, {sour city sollciting and collecting
Agent, and all subscriptions, or other favors extended to
him, willbe duly acknowledged at thisoffice. Jan. ll, 1866.
San Francisco:
Saturday Morning, Jan. 9, 1869.
Notices t0 Correspondents.
Barometer.—No reason seems to have existed for predicting that the present winter would hea very dry one, and consequently adverse to the growth of the
forthcoming wheat crop. On the contrary, 2s faras ordinary appearances have
occurred, reasouing from the analogy of
former years, at least an average rain-fall
for the seasons 1868-69 might fairly he
anticipated. Our rain-fall, and the general hygrometric state of the atmosphere,
is usually found to depend so much upon
the directiou of the wind, rather than its
specific gravity, that the useful instrument whose name you have assumed as a
nom de plume has, with many in fhis State,
almost fallen intodisuetude. Occasions,
however, occur sometimes in which the
indications of that valuahle instrument
may be studied by the working farmer to
great practical advantage. A very instrnetive lesson of the kind has taken
place during the current week, the first
part of which, to all external appearances, threatened a very heavy and continuons rain-fall. Owiug, however, to
the denser condition of the atmosphere
as indicated by the harometer, we were .
only annoyed with dense fogs, which
cleared off as the snn hecame moro powerfnl and approached its meridian. * *
As these remarks were written during the
fine days of the commencement of the
week, superficial ohservers may imagine that the ohservations mado have heen
negatived by the rain-fall which took
place on Thursday evening, which, however, did not occur until a fall in the
barometer lad taken place, and even with
that fact the pluviose element ceased on
the appearance of day.
H. W. O. M., Boise City, I. T.—The name
of the gem is not chisoprase, but chrysoprase; the magazinist reterred to being at
fault. Your Gael scholars will have no
ditliculty in finding the roots of the latter word, The mineral isa leek-green,
translucent quartz, more properly chaleedony, colored hy nickel. From chrys,
gold, and prase, leek,
Communications have been received from
*“*¢, H. A.” Owen’s River; from ‘‘H. M.”
Boise City. ‘‘P. 8.” Batopilas, Mexico,
isin typo and will appear next week.
L. C., Monitor, Alpine County.— Your
suite of rocks and minerals met with in
your tunnel, is interestiug, and will he
attended tu.
Ture New Mints.—Dnring tho past year
the Branch Mint building at Carson City,
Nevada, has heen completed, and the necessary machinery and fixtnres lave been
forwarded, The new Mint at San Francisco will not be longin getting into operation. Its cost is estimated at upwards of
a million of dollars. The entire deposits
at the Branch Mint in San Jrancisco, were
formerly in unparted bullion; now nearly
two-thirds of the amount is deposited in
hars refined by private estahlishments.
Amalgamation with the Aid of Elee-.
tricity--The Nolf Process.
We are enabled, this week, to furuish our
readers with something more definite regarding the Nolf electro-metallurgical process, whereby an electric cnrrent is hrought
to hear to facilitate the desired chemical operations in pan amalgamatiou, under conditions in many respects nearly identical
with the Patio Process. Such is Mr. Nolf’s
invention,—reference to which,in our columns, will he remembered in convection
with a notice of experiments that have heen
making at the Union Fouudry under the
auspices of Mr. Pioche, the especial patron,
and substantial ahettor, of the process.
A numher of metallurgists and mining
engineers were present, at the somewhat
extensive works whieh have heen called into existence for especial development of this
process, ou an extensive working scale, at
the corner of Valencia and Seventeentli
streets (Mission), on Tuesday last, to
witness the first public test of the principles
whose practical application to meet our
great recognized metallurgical waut—a process of gold and silver amalgamation without roasting in presence of hase ingredients—has occupied the close attention of a
nomher of very competent men that we
know of, for months, and even years, so far
as Mr. Nolf is concerned; and the results of
which are now given to the public in a
manner so definite, and so plainly indicative of entire confidence on the part of the
experimeuters, whohayethoroughly tried it
all, and of financiers, too, that we feel justi-}
fiedin calling attention to the process as one .
certainly promising a great deal on that
ground alone; andas worthy, in virtue of
its importance, of the examination ofall who
may he in a position to derive henefit from
the attainment of so important a desideratum.
But the process is really well ‘founded
theoretically, on incontrovertible principles
of science, and ina most interesting department thereof. It is such asone may take
pleasure in tracing, from nseless observed
phenomena into theory, and from generalizations into practice, where it may possibly
he worth its millions to the industries of
@ people—a practice which liuks onv every
day, money-making pursuits, withthe operating foree which lies, as we shall see, at
the very foundation of the philosophy of
all things terrestrial,—to the profoundest
central principle to whose operations
nortal reason has been ahle to trace the
foundations of chemistry, geology and
physics—the very wilima thule of scieuce, where wo hecome alchemists again,
like our metallurgical predecessors the
fathers of civilization iu the middle ages,
but on abasis of enlightened and estahlished truth; a field where, in apprehending the electrical nature and characteristics
of the affinities between simple elements, we find ourselves at the houndary,
still groping in darkness, where we discover analogical principles goveruing the
birth and procedureof vegetahle, animal and
spiritual life. Wearrive at the great and
mysterious first principles of the Positive
and Negative, the giving and the receiving,
themasculineand feminine principles, which
exist as the fundamental moving cause
throughout all nature; from electricity, the
attendant and equivalent of all chemical
action, to like material manifestations
of a more suhtle character, couceruing
the higher laws of which we are uot yet
able to generalize.
It was Becquerel, the renowned author of
“Traite experimentale de I ectricite et du
magnetisme” (1834), who, in the midst of
his enthusiastic labors in this field, first
sought to take advantage of the facts that artificial electricity will facilitate not only .
chemical decomposition of compound sub-.
stances, hut also re-combiuations, under
certain conditious ; that the metallic elements are all relatively to each other positive and negative, in the order (according
to Berzelius and others), from positive to
negative, of the earths, zinc, iron, lead,
tin, hismuth, copper, nickel, silver, antimouy, mercury, platina, gold; heing conductors of electricity, and of heat, in nearly
the same order; that when they are put
together in a tuh, and a current of electricity is led through the same, they are
attracted and caused to move, relatively
and respectively towards the positive and
negative poles, in the same order and relation to each other.
Non-metallic elements ohserve the same
law ; the simplest illustration of which is
the decomposition of water in putting the
positive and uegative wires into it, the oxygen gas gathering aronnd the positive pole,
and the hydrogen aronnd the negative, so
that they may he caught in inverted glass
hells, and tested, by hurning separately,
showing a difference of color in the flame,
etc.
The salient laws, touching this electrometallurgical process, were developed,
however, hy unmerous others hesides Becquerel. It was only iu 1800 that Galvani
and Volta discovered galvanism — chemical
electricity—; theu Brignatelli made a long
list of experiments showing how the fluid
would decompose different salts, transferring the elements to different poles; aud
Cruikshank, the discover of the galvanic
battery, observed how the metals in acetate
of lead, sulphate of copper, nitrate of silver, etc., were separated out, or ‘‘revived,”
as the expression was,
Becquerel established metallurgical works
at Greuelle, near Paris, and labored enthusiastically in the attempt to make some
practical use of these remarkablo principles, hnt without success hy the dollar
eriteriou (which governs metallurgy as inevitably as does natural law)— and others,
hoth wise and nuwise, have tried it since,
with various results, the history of which
would occupy too much space to he gone
over in this counection. Dingler’s Polytechnic Journal, and the Berg und Hittenmannische Zeitung have had accounts of recent attempts,iu Europe. Tam Mining
anp Screnriric Press, page 306, Vol. XI,
contaius an account of various trials in
connection with amalgamation, at Gold
Hill, and other places iu Washoe, at different times, and within afew years. Amongst
the experimenters were John A. Scott, 8.
Kean, B. R. Norton, Col. Brevoort, and
others, both in this city and in the State of
Nevada.
Mr. Nolf is not a new experimenter in
this matter. He has heen coguizant of all the
difficulties that were cneountered, and has
labored with very creditable perseverance
in his endeavors to overcome them. He
was himself a pupil of Becquerel’s, from
whom he proudly acknowledges that he obtained his ideas, while bis own success and
the ercdit. to which he is entitled, are to
depend on the degree of making the
same practically and ecouomically available. How far California will he indebted
to Mr. Nolf, we hope to beable to show
hereafter, by further details of practical
tests at his works, than weare able to find
room for at present.
The establishment atthe Mission consists
of a large working room; a pan, or rather a
tuh, heing of wood, of large size, to contain and manipnlate the ore; a very powerful voltaic hattery, of about forty vessels,
arranged on a table aloug oue of the walls;
a laboratory in an adjoining room; a nnmber of tanks outside, to wash the amalgam;
and numerous tuhs, tanks, crushers, with
assaying tools, etc.
Asan illustration of the basis of the process,
our attention was first called to an interesting experiment, made with some quicksilver in a large porcelain dish containing also
salt water. The two poles, represented by
the two wires of the battery, were hrought
into the salt water on opposite sides of
the quicksilver; the result was, that the metallie substance eagerly ran to the negative
pole, and followed it wherever it went.
Then the negative pole was taken out, and
the positive pole put into the middle of the
quicksilver bath; immediately its surface
hegan to taruish, to coat over, whitening
and hecoming variegated with chloride of
mereury (calomel, Hg? Cl) which increased
sorapidly that it must finally have destroyed the quicksilver. But the wires
were now placed again as at the heginning,
and iu half a minute, with a little stirring
from the negative pole, the calomel was entirely decomposed, and the quicksilver was
as bright as ever. During all this there
was a very distinct smell of chlorine gas,
arising from the decomposition of Na Clof
the salt water. It was remarked, as a point
that might have some influence in the Nolf
process, that the separation of chlorine
might leave the sodium in a condition to
form sodium amalgam; hut it is douhtful
asto whether the sodium would not he in
an oxidized, rather than ina metallic condition.
Next a quantity of sulphate of copper
was poured into the dish. While the electric
curreut was applied, no result was ohservahle, but from the time it was removed it
was not long till the quicksilver was almost
entirely destroyed hy the chemicals; the
coating heing darker and thicker in this instance than in the previons one, and the
destruction more rapid. Here hi-chloride
of copper (Cu Cl) was formed, with the ealomel on the snrface of the quicksilver, and
sulphate of soda in the solution. The wires
were now applied once more, and in a few
minutes the quicksilver hath was as clear as
hefore; the effect of the electric current
having heen to reduce the hi-chloride of
copper to the suh-chloride (Cu? Cl), which
is harmless to the quicksilver. Electricity,
therefore, prevents the formation of
the destructive bi-chloride of copper in
amalgamation, orif the same he formed, reduces it.
As the chemicals used are the same, in
operation andin fact, as the salt and the
magistral used in the patio process, these
experiments will be admitted to have a definite value. Itis true that the chemistry
of the patio process is explained in half a
dozen different ways; hut the ordinary one
is that the bi-chloride of copper acts on the
snlphide of silver, and the elements interchange, forming sulphide of copper, and
chloride of silver: (Cn Clt+Ag S=Cu $+
AgCl).
Concerning the operations in the pan or
tub, there were put in 700 pounds of Alaeran (Copala, Mexico) ore, consisting of
mixed sulphurets of iron, copper and silver; a very complex, refractory, roasting
ore, which cannot be treated at all by the
patio process. After 20 to 24 hours of
working with this ore, they have ohtained
80 per cent. of the fire assay. On a smaller
scale they have obtained 92 per cent.
The tub is, of course, insulated as well
as the battery, standing on glass plates. A
simple stirring apparatus revolves in the
tuh (by band power: at present) and the
negative wire connects with this, heing so
arranged that the current runs down on
the copper covering of the stirring arms,
and thence passes through the pulp to the
inner surface of the tub, which is copper
lined, for the purpose of affording a couductor. The hottom is of wood.
In working, the quicksilver being at the
bottom, and there being no grinding, little
particles gradually heeome detached by
mechanical mixture with the pulp, and follow the stirring arms in virtuo of their
electrical attraction till the entiro pulp has
been searched, and the amalgam finally is
collected as much as the friction will admit, on the stirrers.
There was an evident tendency of the
amalgam formed in the tuh towards the
stirring arms, or negative pole. It could
he sliced off, after a few hours, with a
knife. On acenmulating to a certain thickness, some of it would fall off, but the
electric action is in no wise hindered,—ou
the contrary strengthened, by the thickness of this coating, precisely as is the case
in the electrotyping process,—which might
have been referred to in many other respects in illustration of the priuciples here
deserihed.
Of the actual chemical decompositions
that took place in the pan, we may say
something hereafter, thongl that question
ean scarcely he met by anything more than
conjecture at present. We know that chlorides aro first formed, and these are then
amalgamated. r
In washing the pulp, after amalgamation,
it is run over ecoppor plates charged from
an electric battery. The little particles
which are ordinarily so apt to be washed
away, are thus powerfully attracted to the
copper plates and casily induced to separate themselves from baser substances.
We intend to report the progress of this
important process from time to tlme.
Oe
OrricE Removau.—The office of the Mohawk and Montreal Mining Company, Nevada County, has been removed to this city,
No. 414 California street, hy vute of the
stockholders.