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Volume 24 (1872) (424 pages)

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Page: of 424

April 20, 1872.] SCIENTIFIC PRESS. 243
eed ag
MECHANICAL ‘PRoGRESS
Utilization of pita Clippings (Tinners’ Waste).
Tin-plate consists of iron covered with puro
tin, or an alloy of tin and lead. The iron is
of very superior quality. Thotest to which it
is submitted is that it must bear bending at a
sharp angle withont cracking, and when hent
nnder the hammer light must not shino throngh
any creviccs along tho line of flexion. The
proportion of tin in tin-plate varies according to
quality from 3 to 7 per cent. The valuo of tin
in tho waste is about eqnal to that of the iron.
Several methods for treating tinners’ wasto
have already heen dovised. In 1848, Schunk
proposed three processes, of which the firet
was to boil the clippings in sulphide of sodium,
tho second to boil insoda-lye, in which litharge
was suspended, aud tho third to heat in a
lye of chromato of potash and caustic-potash.
In 1854, Jas. Higgin patented a mixture of
hydrochloric acid, and solution of nitre, hy
which means it was expected that the tin would
bo dissolved with less action npou the iron than
in hydrochloric acid alono. In 1857, Parkes
proposed to put tho clippings into mercury in
a revolving shect-iron drum, and thus colloct the tin in an amalgam. In 1863, Paterson
patented a process for mixing the clippings
with fused lead so as to form solder. By heating the mass again, the alloy is fused off.
Standevant and Harman proposed to melt off
the tin in a current of steam and hot air into
an iron cylinder below; but all these methods
seemed to present some radical objection.
A perfect method for treating tin cuttings
should fulfil four conditions. 1. The iron
mnst bo free from tin, 2. The tin must be obtained in a marketable form, and preferably in
the metallic state. 3. Large quantities must
be capable of treatment at once without much
labor, 4. Tho proccss muet be cheap. Iron
containing 0-5 per cent. of tin, thongh it can
be forged and welded is very cold-short. It has
a fine-grained steel texture, a clear ring and
great hardness, but can be useful for very few
purposes. None of the old processes, except
that of Higgin, thoroughly remove the iron.
Schnok obtains the tin iu an nnsaleable form,
and hls process can be used on a small scale
only. Mr. Ott has recently devised a method
which has been applied to 300 tons of clippings in three months. The tin waste is put
into a drum of thick copper, provided with
holes %-inch in diameter, and two inches
apart. It contains 1,000 ths. of clippings. It
isthen made to revolve in a bath of acid in
which the tin is dissolved off. Then the drum
is lifted out by a crane, and made to revolve in
@ water-tank, then in an alkaline bath and then
in water again. In the acid bath it revolves
according to the amount of free acid, from 5 to
50 minutes, and in the others 5 minutes each,
making with the time spent in lifting the drum
a total of 70 minntes. So, as the drum contains 1,000 ibs. of clipping, it is possible ina
day of 10 hours to treat 90 ewt.
In the acid, the tin, the lead, and ahout5
per cent. of ironare taken up. This solution
is let off intosuitable tanks. The lead is separated first, and then the tin is obtained in a
state of purity, by putting in plates of zinc,
when it is thrown down either in a crystalline
or a spongy form. It is well washed, fused and
sold as block tin. The zinc remains in solution, one part of zine being required to precipitate two of tin. The mixed solution of
zine and iron may be used for preserving wood,
or for making coarse colors for house-painting.
The iron plutes are sold to the iron works.
Dorn proposes to pilo up tin clippings in
chambers of a suitable material, and to dissolve
off the tin by means of a gaseous mixture, On
this process, it may be remarked, that though
the bichloride of tin is extensively used by
color-makers, dycra and calico-printers, it is
necessary that it should be perfectly free from
iron.
The Production of Bright or Lustrous
Colors on Metals.
The active chemist, C. Puscher, of Nuremburg, proposes a new method of coloring
metals which can be executed quickly and
cheaply. He produces on those surfaces a coating of metallic sulphides analogous to those
found in nature, as for example, sulphide of
lead. These very stable snlphur combinations,
as is well known, are not affected by ordinary
agents. According to Puscher’s method, in
five minutes there may he imparted to thousands of brass articles a color varying from a
beautiful gold to a copper red, then carmine
red, then dark, then analine blue, to a blue
white, like sulphide of lead, and at last a reddish white, according to the length of time
they remain in the solution used. The colors
possess the most beautiful lustre, and, if the
articles to be colored have been previonsly
thoronghly cleaned by means of acids and
alkalies, they adhere so firmly that they may
be operated upon by the polishing steel.
prepare the solution, dissolve 144 ounces of
hyposulphite of soda in one pound of water,
and add 14% ounces acetate of lead disaolved in
half a pound of water. When this clear solution ia heated to 190° to 210° F., it decomposes
slowly and precipitates sulphide of lead in
To .
brown flocks. If metal is now present, a part
of the sulphide of lead is deposited thereon,
and according to the thickness of the deposited
sulphide of lead tho above mentioned heautiful
lustro colors aro produced. To produce an
even coloring, the articles to he elon must
be evenly heated. Iron treated with this solution takea a steel blne color; zinc, a brown
color; in the case of copper objecte, the first
gold color does not appear; lead and zinc are
entirely indifferent. If, instead of the acetate
of lead, an cqual woight of sulphuric acid is
added to the lyposulphite of soda and the process carried on as before, the brass is covered
with a very beautiful rod, which is followed by
a green, which is not in the first mentioned
seale of colors, and changes finally to a splendid brown with green and red iris glitter; this
last is a vory durahle coating, and may find
special attention in manufactures. Very beautiful marhleized designe can he produced by
nsing a lead solution thickened with gumtragacanth on brass which hae been heated to
210° I’., and is afterward treated by the usual
eolution of sulphide of lead. Tbe solution may
be used soverul times, and is not lable to spontancous change.— Technologist.
Glass Bearings.
The uso of glass bearings for the wearing
surfaces of cross-beads, pistons, and other
working parts of machinery which has recently
hoon introduced into some parts of the Eastern
States is steadily extending and gaining favor.
These Bearings consist of pieces of glass inserted into the hearing surfaces as hereinafter
described. In the slides of the cross-head they
are simply imbedded ia holes drilled or cast to
receive them, and in piston rings they are in
serted in grooves turned in the rings. The following directions are given by the manufacturer for pntting in such bearings:
“Drill the holes full one-fourth of an inch
larger; in diameter than the glass is, and at
least one-sixteenth deeper thau the glass is
thick. The holes should be chipped nnder
with a center chisel in soveral places in order to
hold the babbit well. Then take a parallel
pieco of iron largo enough to cover tbe hole,
and perfectly smooth on one surface, place a
little oil on the smooth surface and press the
piece of glass to it. By this means you exclude
the air, and the glass and iron will stick together firmly; this is done in order to hold tbe
glass up from the bottom of the hole, and thus
allow the babbit to run under as well as around
it, forming a perfect bed for the glass to rest
on. Place the piece of iron with the glass fast
to it over the hole}in such a manner as to keep
the glass in the centor, and also leave a small
space uncovered through which to pour the babbit. The glass should be above the surface of
the working part, in order to take the full bearing. Place at least one thickness of writing
paper between the parallel piece and the other
surface; clamp the parallel piece to the gibb or
other part, for if not clamped the glass is
likely to rise too high above the surface while
the habbit is being poured. Caulk the babbit
in several places with a blunt center-punch between the glass and iron, theu scrape it down
to tho surface. Bearings put iu locomotive
cross-heads should not be more than flush with
the surface.
To insert tho bearings in cylinder packingrings, eccentrics, etc., a groove should be cast
or turned in the center of sufficient depth and
width to allow the babbit to run under and
around the glass; the groove should be turned
nnder and also chipped rough on the sides,
Then bend a strip of sheet-iron to the exact
radius, and make the proper surface smooth,
then stick five or six pieces of glass to the
smooth surface by means of putty or any other
substance that will stick well. Then clamp the
sheet iron with the glass fast to it to the ring
or other part; close up one end with putty, and
pour the babbit inthe other end. When the
plass is all inserted, take oil and emery with a
file and grind the glass down to the surface,
making sure that not one of the glasses are
above the surface when the ring is finished.
In parts where there is not sufficient thickness of material to allow the babbitt metal to
he run under the glass, one thickness of muslin may be used as a bed for the glass to rest
upon.”
These bearings are now very exteusively used
in locomotives and stationary engines, and the
manufacturer is furnishing them to all parts of
the country and for all kinds of steam-machinery. Most persons, we believe, would be surprised to find how much rough nsage a piece of
glass will bear if properly embedded in a soft
metal. If they are well fitted they will stand a
considerable number of quite severe blows from
a hammer without being fractured.
THE manager of a furnace in Prussia, fiuding himself without fuel, resolved to kcep the
fnrnace alive as hest he might. He hegan at
once to reduce the charge of iron ore to onehalf, keeping all the whlle the nsual charge of
coke, and after the furnace was thus filled, the
blast was cut off, and all apertures were closed
as air-tight as possible, and watched carefully
so for more than ninety days anxiety. A regular supply of fuel being once more secured,
after that time, the tuyers, hearth, and top
wero reopened, the hot blast let on, and twelve
hours later the first clean cinder made its appearance, flowing over the wall-stone, to the
great delight of all concerned.
A Prussian engineer has, it is aaid, invented
a machine which will manufacture ice withont
chemicals, merely by compression and explosion of air,
ng f
HCIENTIFIC Progress.
Tue Speernoscore ox tne Nesutar HyrotuEsis,—Tho existence of immense nebulous
masses, from which Laplace snpposed the solar
system to have heen derived, was thought to
have been proved basclees by the iucrcased
power of modern telescopes, which havo resolved into clusters of stars many objects supposed to have been nebule. But since the
spectroscope has been so improved as to he
practically employed for determining the character of such distant bodies, the nvbulous thoory
is again coming into favor, if indeed it may not
now he considered as fully established on a
stronger foundation than ever hefore.
Prof. Kirkwood has made oxtended ohservations in this direction, in which the evidence in
favor of the hypothosis is decidedly cumulative.
Even progressive changes in the physical condition of eome of the aebulm have heen quite
clearly indicated. In some parts of certain
nebulw nuclei have been established—the mass
of gaseons matter evidently passing from ite
attenuated form into a semi-solid state. The
speetra obtained prove this fact beyond the
possibility of douht. This clasa of spectra reveals a constitution similar to that recently
observed in certain comets belonging to onr
own system.
Vetociry or Mrreorre Srones.—It has been
quite satisfactorily proven that meteors, before
they meet with the retarding influence of the
earth’s atmosphere, often move with a velocity
several thonsand times that of a cannon ball at
the instant of its discharge. If a cannon ball
could be made to move with such velocity it
would almost instantly be destroyed, and disappear ina streak of flame. It is probable,
however, that the impetus necessary to impart
such a velocity would at once reduce to powder
any brittle substanco like cast iron or stone.
Meteors which enter the atmosphere at any
considerable angle from a direct line toward its
center are deflected from their course and soon
move from its influence. Such is no doubt the
caso with many which are seen to flit across
the sky; while many, if not most of those whicb
enter in a direct line, are dissipated into impalpable gasses before they have passed half
the distance from the solar bounds of the atmosphere to the earth, or reach the earth in a
state of impalpable dust.
Eruption oF MrrroritEs rrom TEE Sun.—
The theory of a solar origin for meteorites,
however strange and startling it may at first
sight be, cau by no means be condemned as
altogether illusory. Advocated by Mr. Proctor
in Fraser’s Magazine, for April, 1871, much evidence in its favor has heen supplied by the recent solar researches of Secchi, Young and
others. In brief, it is, that the solar prominences result from the shooting forth of liquid
or solid masses orstreams of matter, and that
metcoric masses, or at least some meteorites,
may have originated in this manner, being propelled from beneath the surface of the sun.
Mr. Runyard, in a recent communication to
the Royal Astronomical Society, discussing the
nature and origin of the upheaval of eruption
prominences, states as his conclusion that the
observed phenomena, and all other considerations, go far to render it probable that meteors
are formed from the metallic vapors hurled
from the sun or other stars, or that solid masses
may be so hurled, in eruption prominences.
Mr. F. A. Fleming also remarks of this theory,
that, offering as it does a possible account of
the genesis of prominences and meteorites, it
appears also to contain the germ of another
hypothesis, which he develops, respecting the
cause of the connection between solar eruption
and terrestrial magnetism.
Tur Transtr or Venus.—Professor Henry
and other scientific men connected with the
Smithsonian Institute and the Naval Observatory haye nnitedin an interesting memorial to
Congress urging the appropriation of $150,000
to make extensive and tborougb preparation
for observing the transit of Venus across the
sun, which will take place in 1874, which is
looked upon as the most important astronomical event that has occurred for many years.’
The last transit was in 1792, and excited so
much interest in the scientific world that seyoral European Governments made liberal appropriations to enable their astronomers to
take observations. The transit of 1874 will
not be visible in this country, and will be
best seen from the islands of the South Pacific
and Indian oceans. It is proposed to send naval expeditions to those points, accompanied
by scientific parties. The Governmeuts of
many of ,the conntries of Europe have already
taken steps to this end, and there is little douht
that Congress will enable the astronomers of
this country to have the same advantages as
their foreign hrethren.
Tue proposed tunnel nnder Mt. St. Gothard
will be ahout twice as long as the Mt. Cenis
tunnel, andit will pass under peaks varying
in hight from 8,750 feet to 10,000. The principal advantage anticipated from the work is an
increase in the facilities for trade and travel
between Europe and Asia, by way of Italy.
Passtvirr or Inox, CapMivm, aNp Trx.—Many
yeurs ago Faraday pointed out that when iron
was plunged into nitric acid sufficiently concentrated, it became possessed of a surface condition which rendered it indifferent to the strongest acid; and which enahled it to form a voltaic
circuit with ordinary iron. That such iron has
really heen decidedly altered in character is also
evinced hy the fact that it refuses to reduce
copper from solution of its salts. Dr, Schin
has observed that if cadmium is wrapped round
with some platinum wire, it may be placed in
strong nitric acid without being in tbe least degroe acted upou; but if tho wire is removed the
cadmium is instantly attacked, thus showing
that the passivity of the cadmium is entirely
due to its contact with the platinum. The
author also states that when tin is treated in a
similar manner it exhibits ike pheuomena.
Daxcrnovus Gas Prprs.— The Journal de
UEclairage notices an accident which gives new
proof of tho danger attending the uso of copper
gas pipes. In April last, a workman haviag
with a triangular tlle ent almost half through a
gas-pipe of red copper 3% inch interior diameter, which supplied the Liege station, was removing the tool, when an explosion took place,
with a noise like the report of a rifle, and the
workman wae much burnt. A similar accident
happened subsequently, hut with lessintensity,
and the workman, who was not injured, did not
report the circumstance. Some gas-pipes having heen taken down, they were found covered
with a blackish coating, and they showed evident signs of corrosion from ammoniacal condensation. The hlack matter was analyzed,
and was found to consist of acetylide of copper,
which explodos between 203 deg. and 248 deg.,
producing water, copper, carbon, carbonic acid,
and traces of carhonic oxide,
Tue Esry Rar Tueory.—It is stated that
notwithstanding the continued and wide-spread
fires which prevailed for four or five weeks in
Northern Illinois, last summer, devastating
forests over a large area, not a drop of rain
fell, as might have been expected, if the Espy
rain theory is correct. The rain only came
with a change of wind to northward, and seveee after the worst burnings were over
witb.
On the contrary, heavy rains followed immediately after the great firoin Chicago. Possibly the occurrence of rain in the latter instance
was due to the greater intensity and concentration of heat.
UNEXTINOUIsHABLE Sianat Lawp.—Some experiments have been made in Tamise, with the
unextinguishable self-lighting signal lamp of
Holmes, and they promise a great snccess.
The lamp is a cylinder of tin, with a conical
top; the cylinder is filled with phosphuret of
calcium, prepared by the inventor. When the
lamp is plunged in water, this quid, entering
the cylinder, effects the decomposition of the
phosphuret; phosphuretted hydrogen is disengaged in large quantity with vapor of phosphorus, takes fire spotaneously, and burns with a
brilliant flame.—Les Mondes.
Crzanstna Woor. From Burrs.—The wool is
soaked in a bath containing 2 ibs. alum to every
10 ibs. of wool and to this sulphuric acid added
untilthe bath marks 6 deg. B. In this bath
the wool shonld remain until its appearance
shows that the bath has had its effect, when it
must be taken out and thoroughly drained. It
is then subjected to the action of a brushing
machine which removes all the burrs.
THE GREENLAND Meteorites. — Professor
Nordenskiold states that the masses of meteoric iron brought from Greenland by the recent Sweedish expcdition soem to have formed
the principle masses of enormous meteoric fall
of miocene date, extending over an area of some
two hundred square miles, The iron appears
tobe free from silicates. Professor Ramsey
thinks the masses may be of tellurie origin.
Aw Acoustic EXPERTIMENT.—Let a wide glass
tube, open at both ends, he taken, and in thisa
piece of fine wire gauze be pusbed up some
little distance. If the gauze isnow heated to
redness over an ordinary Bunsen burner, and
then removed, it will shortly emit a shrill note,
lasting from 5—10 seconds. The experiment
we believe will be new to most of our readers,
and has the merit of always going off.
An EXPERIMENTAL Gas Worrs.—The Germau
Society of Gas and Water Experts have under
consideration a plan for establishing an experimeutal gas works, for the purpose of deciding
various questions which may arise in the details of their profession, by actual experiment.
The proposed plau, if adopted, will be upon a
large scale, so asto reproduce, as faras possible,
all the conditions met with in practice.
Lancs Sun Spor.—Professor S. P. Langley
of the Alleghany Observatory, has computed
the area of one of the spots lately visible near
the center of the sun’s disc, from careful measurement, and found it exceeded 2,300,000 square
miles, which is more than ten times the entire
area of the earth.
Renova of spots made by sugar, from goods
with delicate colors and much sizing. Thespot
should be rubbed with a damp cloth, and then
with a piece of fresh bread, which will remove
the saccharine matter without affecting the
color.
Tue principal supply of bismuth is derived
from Bolivia, but it has recently :been discoyered in Australia.