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Volume 24 (1872) (424 pages)

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Page: of 424

May 25, 1872.] SCIENTIFIC PRESS. 323
poe
§oleNTiFic Proaress.
Relations of Calorific Power of Combustibles to Composition.
During tho Inst session of tho New York Lyeoum of Natural History, a discussion arose on
tho ahovo subject, iu which the present writer
startled most of tho members present by annonucing his conviction of the total fallacy of
the provalent mode of calculating hypothetically
tho calorific value of 2 coal or other comhustible, from its e¢lemeutary constitation. Ho
eluiiued that, iu believing that tho samo elemeuts ina complex mixture, as well as ina
homogeneous compound, oveu when preseut iu
tho samo centesimal proportions, must neods
ive the same heat ou completo combustion, we
ignore all the well-founded and accepted views
of moleenlar dyuamics and thormo-chemistry.
As the prodncts of complete combustion of
carho-liydrogen materials were always molecularly ideutical—that is, carhouic acid and water
—the materials themselves must have had identical molecular constitution origiually, in order
to exert the samo amount of internal disturbanco, while falling into the same new molecular
arrangemeut. He cited many known facts to
snpport his views, which gavo rise to somo discussion, and aroused especial opposition from
the distinguished Presideut of the Lycoum, Dr.
Nowberry, whoremarked that if Professor
Wurtz holieved ho could substantiate these revolutionary ideas, he shonld not panee, night or
day, bnt devoto himsolf exclnsivcly to the task,
tho importance of the eubject being nnsurpassed
by auy other in tho rango of science !
With thie pronmble, we introduce the following extract from a report of recent communication of Schenrer-Kestuer and Meunier to the
Academy of Sciences, ou tho Heat of Comhuetiou of Lignites:
‘«Lignite, the anthors fonnd, is distinguished
from coal also iuthis particular—that tho later
emits a far greater quantity of heat than that
dno to the combnstion of its elenients (carhon
and hydrogen). Attention is again called to
tho fact that it is impossible to judge of sthe
value of a fnel according to its clemmentary composition; all calculations hased upon euch data
are quite fallacions, and the authors prove this
conclnsively by referring especially to oue of
the eamples of lignite they investigated.””—
American Gas-Light Journal,
Carnonizep Sewace.—Mr. Hickey is engaged
in India, says Engincering, in testing the efficacy
of his invention of preserving scwage by carbonization. Tho main features of Mr. Hickey’s
plau are that he collects the gases evolved during carbonization, which he proposes to make
available for town illumination, while the coke
which remains has heen found to he a most excellent deodorizer, and, mixed with the ammoniacal Kquors collected from the gas retorts,
it also forms a valuable manure. The production of gas for Hghting pnrpoees hy the carbonization of ordure is not a novelty, but dates
ne far back as 1686. But whether it will ever
he found practicable to illuminate towns with
gae produced from their sewers is very doubtful. Mr. Hickey’s experiments show that gas
and coke can easily be msde by his process,
but the pecnuiary succees of the manufacture
is not yet scttled. Tho gas has an illuminating
power of ouly 24% caudlee.
TnansaiTTED Raprant Heat.—The questiou
whether equal areas at different points of the
solar surface, transmit equal energy towards
the earth has not been eatisfactorily answered.
The author of Mechanique Celeste, finding by
obeervation that eqnal areas do not transmit
eqnal energies (the ceutral regions transmitting, in opposition to his reasoning, much
greater intensity than those near the border)
explains the matter hy showing that the solsr
atmosphere retards the paseage of the rays
cansing a great diminution of the encrgy of the
radiant heat projected towards the earth. Capt.
Jobn Eriesson, in a series of ingenious experiments with incandescent spheree, described in
full in Engineering, shows the inaccuracy of this
theory.
Far Founp my Breer Yeast.—Iu an article by
Dr. Vogel, rend before the Academy of Science,
in Munieh, after referring to the fact that sil
eereals contain a larger or smaller qnantity of
fatty matter, which is an essential constituent
of the grain, the author describes at length his
experiments made for the purpose of extracting, by the means of ether, the fat contained in
heer yeast, an oil boiling at about 200° Centigrade, specifie gravity equal to 0.901; decomposed when heated above 300° Centigrade, and
yielding acrolcin. The quantity of this oil
fouud in one Kter of the yeast amounts to from
0.2 to 0.3 drams. It appears that this oil is, in
most respecte, eimilar to the fatty matter in
barley.
Evreor or Extreme Corp on Sxow.—Dr
Kane, the arctic explorer, recorded the very
striking and euggestive fact that snow, at a
temperature of forty degrees below zero, F.,
loees much of its anti-fractional quality. He
found it nearly as difficult to draw, slede upon
such enow as upon eand,
Discovery or A New Pruanet.—Prof. James
©. Watson, of Ann Arbor, Mich., writes to the
Journal of Science, that he discovered a new
planet, on the night of April 4th, in the eonstellation Virgo. The planet shines like a star
of the eleyouth magnitude,
Presenvation or Woon.—Gen. Haupt contrihutes to tho May Van Nostrand, a review of
tho chief procusses proposed for tho preservatien of wood, and adds eomoe deductions of
his own. From his experimeuts aud in vestigations ho concludes:
1, Thatso long as tho cells of wood are ocenpied hy air and moistnre, no preservative e0lutious can bo iutroduced, aud the expnision of
ftir and moisture iuust be the first step in any
effective process for preserving timher froin
decay.
2. That water can ho expelled by a loug
coutiuned application of heat, but air ouly by
expausion iu a vacuum, and tho comhiaation of
heat aud vacuum will eecure the wiost rapid expansion of both water and air,
3. That the preservative Hid must ho introdnced while tho cells nro empty, consequently
the process must he carricd on in vacuo.
4. That no pressure, however great, applied
externally to the swfaco of timber, eau forco
any fluid iuto the interior so long as air or water
is contuiued in the cclls. When air aloue is present there may bo penetration to a limited oxtent
superficially, hut water is practically incomprossible. If, howover, the pressure is applied
at one end ouly of a stick, as iu the Boucher‘e
process, a fluid may be forced through and exude from the other cud.
Groxootcan Success.—An iustance of complete suecese in scarch founded on geological
indications has just ocenrred in Swedeu. An
extensive coal bed of unusual depth iu Europe,
aud of excelleut quality, has been discovered
at Raus, in Schonen, by horing on the strength
of evidence afforded hy the Kthologieal formation existiug there. At first the promises were
uot satisfactorily fulfilled. Eleven strata of
coal, indeod, were pierced hy going down 566
fect; but none of these were more than a foot
or so in thickuess. Five feet further a bed
was peuetrated over eight feet thick. Other
horiugs prove tho oxistenco of coal of great
extent. ‘he shares of the eompauy at ouce
rose 700 per ceut ahove their par value,— Ex.
Penuyian Annquiries.—The Geological musoum of the University of Rome has received
from King Victor Emauuel a magnificent collection of Peruvian antiqnities, comprising a
number of silver vases, eome extremely curious
musical iustruments, a colored garment made
from the hark of trees, and eome arrows
and lancee. Theee last are notehed, ornamented with feathers, and have wooden
heade, ehowiug that thoy helong to tho period
when the use of iron was unknown. The
whole of theso ariicles were found in a bed of
guano, and evidently date from the earliest antiquity.
Bomer Incrusration.— Expcrimente have
been tried with favorable results, itis said, at
Vienna on Bérenger’s plan of treating feed
water for boilers. The water is softened hy a
eolution of lime and forced through a particular kind of filter, which retains the generated
precipitate. There is no uecessity for waitiug
for tho settling of the precipitate. From 10 to
15 filters, each of 0.1 cubic metre capacity,
eoften ahout 410 cubie metree of water per day.
Ant Monuments.—M. Demctrio Salazaro, the
Iuspector of the National Musenm, at Naples,
is about to publish, in thirty parts, at fifteen
shillings each, a seriee of photographs and
ehromo-lithographe of the Art Monuments of
Southern Italy, from the fourth to the thirteenth century. This is the first great attempt
of its kind, and is intended to show the growth
and development of Italian art from its earliest
ries.
Tue vacancy at-the British Geological Survey office, cansed by-the death of Sw Roderick
I. Murchison, has heen filled up by the appointment of Professor Andrew Cromhie Rumsay,
L.L.D., F.R.5., as director-general. Professor
Ramsay hae for many years heen director of the
Geological Survey and Profeesor of Geology in
the Royal Sehool of Minee.
A RemaRraBLe Miygrau.—A. Frenzel writes
of a mineral,which forme in the winter in the
Himmelfahrt mine at Freiberg, but vauishes in
the spring, when the weather begine to grow
warm, or damp, though it forms 334 metree helow the surface. An analysis gave
Magnesia........... co eno canogee 16.53
Sulphuricacid..
WOU eae se oe
Tux Spectroscopic Assoeiation of Italy is the
title of a new society, the main object of which
will be ‘‘to enrich science, by the aid of the
spectroscope, with new discoveriee upon the
physical constitution of the suu.”’ The first
number of the Memoirs of the Society hae
already been published.
Xynownrre, which ie prepared by the action of
nitric acid on woody fibre, is made into a sheeting or tissuo impermeable to water, which may
be used as a suhstitute for india-rubber in the
manufacture of all water-proof articlee.
Repeaten spectroscopie measurements made
last year by Professors Zollner and Vogel, in
Germany, show that the velocity of rotation of
the sun on its own axie is at the rate of six hundred and sixty miles an hour.
Cane-suGAR when exposed to light in sealed
tubee ie conyerted into grape-sugar or glucose.
The eolution should be os concentrated ae
possible.
MecHaN ICAL Progress
Economy of the Hot Blast,
The first practical application of tho hot
blast was mado iu 1828 or 1829 by J. B. Neilson,
an Englishmau. Mr. N. and his colleaynes
after determining the great value of tho invention for smelting ores, expeeted to seo it generally employed for all furnace operations; but
the result has been that practically, it is almost
exclusively confined to smelting the orcs of
iron,
Tho earliest carefully recorded experiments
with tho hot hlust wero made at tho Clydo Iron
works, with the following result:—
Forthoyonrecmtcressses+s. 1829 1831 3833
‘Temporatary of blast. Cold ahr EF, Gl2*F.
Coal used per ton of i: As coke. As coke. In raw stato.
For fusion, owt. hs St 40
For hvating air, raw coal.. nil
For blowing onginus, coal. 20
153
8
n
59
wy 7
From this it would appear that heating the
air with 5 ewt. of coal had saved 47 ewt. of
fnel in the furnace, and 8 evwt. similarly applied
had beeu followed with au ecouomy of 93 ewt.,
or ahove 69 per cent.
Besides this advautage the mako wae iucreased by more than one-third, and a blowiug
eugine, which only supplied three furuaccs
with cold blast, was equal to four when the air
wae heated.
The iron trade hesitated somewhat in creditthat the heat generated from 8 cwt. of fuel
burnt outside the furnace, should be able to
perform the duty of o very much larger weight
burnt inside. Some writers on tho metallurgy
of irou, wheu speakiug of the advantages of
Neilson’s system, have not perhaps beeu sufficiently careful in drawiug a distiuction betwcon
the saving directly due to ite application and
that arising iu a collateral manner from its
use. Looking at the question, however, in its
commercial sense, the figures and lauguage
quoted from the work of Dufrenoy justified the
character he gave to it.
Puddling Steel Rails.
The Flushing and North Side Railway Company with its leased roads will have laid, hy
the let of July ucxt, 40 miles of oteel track.
The rails are of puddled oteel, with partly iron
flangee and vertically piled. .
The advantages claimed for these rails are:—
perfect safety agaiust breaking, nota single
rail of this kind haviug been broken duriug
twelve years’ use in Germany and four years
use in this conntry, greater strength and enduranec than can he obtaiued from steel-capped
raile.
The valuo of the worn-out puddled-steel rails
is higher in proportion to first cost than that of
cast-eteel raile, or iron rails with cast-steel caps,
which cannot be re-rolled, but must be recast.
The only disadvautage of the pnddled-steel
rails is that a percentage of them may give out
in the weld after a wear ahout equal to that of
the life of three common iron rails. Thisis
only a disadvantage in comparison to full steel
or ingot rails, which have no welds, and therefore cannot failin the same manner. Setting
aeide the greater safety of the welded steel rails,
the question of economy in the use of either
chicfly depends ou their respective first cost,
on their wearing qualities, and on their market
value as scrap when worn out. The solutiou
of this question will depend more or less on
the individual experience of the consumers, especially of those who have tried the different
kinds of steel rails.
° Lele
RarinoapD y Improvement.—A Pennsylvauia
engineer, named Wilder, has recently hit upon
an idea which, if carried out as it deserves to
be, will do much toward increasing tho efficiency
and enhancing the economy of railroads. It
providee for the laying of two narrow gauge
tracks, eide by side, with a epace between the
inner raile equal to the ordinary gauge of four
feet eight inches. Thus three possible gauges
will be furnished on the same line, all of which
it is proposed to use. Tor freight, the narrow
gauge will be ueed at a safe rate of specd, while
for passenger travel, and a high rate of speed,
the broad gauge will be used, the cars being
mounted on four lines of wheels. This, he
contends, will preveut oecillatiou, thereby inereasing safety. He calculates by this system,
and the increased weight of engines, it will
permit of a rate of speed being attained ae
high as a hundred miles an hour.
No doubt a greatly iucreased speed may be
attained by eueh a device, hut when a train of
cars is made to trayel a hundred miles an hour,
the material of which they are constructed and
their manner of coustruction must be somewhat modified from their present material
and form.
Punntine py PetroteuM.—It ie asserted by
the French technical journals that the experiment of using petroleum as fuelin the puddling
furnace which has been in progress iu a large
iron producing estahlishment during the past
three months, has proved itself to be vory succeseful. In poiut of couvenience, efficiencyand
in the euperior qnality of the iron prodnccd, it
is asserted that petroleum affords the best fuel
that has yet beeu employed.
Burnt Iron and Steel.
W. M. Williams has given the result of some
iuquiries into the causes of this phenomeuon,
to the Chemical Society of London. After
some remarks upou the physical characteristics
of iron and steel eo damaged, he assorta that he
fonnd in all the samples of hurnt iron which ho
has subjected to examination, particles of hlack
oxide more or less abuudantly distributed
throughout the mass. Theso are, however, absent in burnt steel, The method which he suggests of quickly detectiug such damage, is to
tako a sinall quantity of fresh borings or filings
from the subjected metal, cover them with diInted nitrie acid. As tho iron diseolves, the
free oxide separates and remains suspeuded in
the liquid, rendering it dark in color. These
particles shortly disappear, aud are thus to be
distinguished from separated carbon. No such
discoloration tukce place with good iron.
The cause of the hurning of iron he explsins
as follows: As soon as tho small quantity of
carbon is removed from tho heated mass hy oxidation, this procees exteuds to the iron itself—
not ouly upon the surfaco, but into the interior.
The higher tho temperaturo, and the longer the
exposure, the greater is the quantity of carhon
necessary to protect the iron. The best iron
is that iu which carbon is bronght to tho lowest possible proportion, without oxidation of
the iron.
Burnt steel the author considers to be steel
which has, by reheating, lost some of its carhon
by oxidation, and by suddeu sohdification has
had the resulting carbonic oxide imprisoned iu
theinterior of its mass, The well known permeahility of irou for certain gaeee renders snch
a proccss not difficult to understand.
The structure and properties of “ burnt iron
and etcel,’’ are therefore ‘‘ caused by the presence of intermingled particles of combustion
products breaking the continuity of the metal.
‘The carbon is hurnt in the case of the hurut
steel, the iron itself in the hurnt iron.
Tue TurnIne PRopeLLer.—As a gun recoils
when fired, or ae the progress of a rocket is
kept np by the recoil arising from the efflux of
the gases geuerated hy the ignition of the compositiou with which the rocket is filled, eo the
progrees of a veeeel driven by the turbiue propeller ie kept up hy the recoil arising from the
efflux in a eternward direction of a stream of
water, kept up by the action of a contrifugal
pump or turbine, driven by a steam engine,
drawing water from the sea and dischargiug it
sternwards, in a continuous stream, through a
bent pipe or nozzle, at a high velocity,
The turbine propeller was iuvented eome
years ago, and attracted snfficient attention to
secure a competitive trial by the British Government in 1867, with ecrew prepellers, Although the turbine did not equal (although not
much behind) the screw, yet its performance at
so early a stage cannot but he considered as
very promising. Mr. A. Murray hss lately
brought up the subject again in the Jour. 2.
U.S. £, and urges further triale and inveetigations. It ie claimed that the turbine affords
a higher per cent. of utilized power than the
paddle or screw, which laet, all admit, lose a
large amount of power, say 40 to 50 percent. at
least, while centrifngal pumps of 40 to 50 horsepower, for raising water, have been found to
utilize even as high ae 80 per cent., varying
from that dowu to 50. But to determine this
point satisfactorily further experiments are
needed.
Other pointe of superiority over the ecrew or
paddle wheel claimed for the turhine are: the
power of rapidly etopping the way of a vessel;
great power over a heavy leak; freedom from the
chance of internal injury or of fonling; nitility
when the vessel is being driven by sails at the
rate of 10 knots or more, (when the paddle or
screw would be of little or no service, ) thus obtaining a greater speed than ever yet realized
on the ocean; nesistance rendered to the veesel’s steerage; not being affected by the pitching or rolling of the vessel; nou-interference
with any desired form of the ship for insuring
good sailing properties; facility of bringing into
action or discontinuing its nse, ete.
Pressune IN Steam Borers.—The question
as to whether the pressure in asteam boiler was
equal or different at top and hottom, concerning
which their eeeme to be eome difference of opinion amongst engiueers—though it is difficult,
from the eimpKcity of the facts involved in considering the question, to see how a differeuce of
opinion should exist—has neverthcless been
experimentally determined by the Messrs. Hunter, at their establishment in this city. Au elbow was attached to the end of the blow-off pipe
which eutered the mud-drum; into this a plng
was screwed, and tapped to receive a half-inch
pipe; to this a steam gange was attached and
the cock opened. On comparing the indications
of the ganges attached at top of boiler and to
the top of drum, ae above deecribed, it wae
fonnd that the pressure was greatest at the bottom, by a pound and a half, proving, as might
readily have been predicted, that the pressure
upon the bottom ofa boiler ie equal to the
eteam proseure indicated above, plus the weight
of a water column eqnal in hight to the difference in level hetween drum and surface of water
in boiler, and in diameter to that actiug on the
gauge.—Jour. Franklin Institute.
Up to 1870 there were seventeen steel works
in Great Britain. There are now nine steeltail mills in the United States, while two othere
are building at Chicago and Springfield, Ill.,
and four others are projected at St. Louis, Milwaukee, Omaha, and two on the line of the
Pacific Railroad.