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Volume 29 (1874) (428 pages)

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Page: of 428

194 MINING AND SCIENTIFIC PRESS.
[September 26, 1874.
Refining Base Bullion.
A correspondent of the Eureka Sentinel gives
the following description of his visit to tbe
Germania Refining Works, situeted about six
milee south of the Salt Lake city, on the Utah
southern railroed. The main objéct’ of. these
works is the separation of the precious metels
from the leed in the so-celled base bullicn, by
means of zinc, or, technically speeking, the
desilverization of lead by zinc. As it may not
be nninteresting to a large number of yout
reeders to get an idea of the exeention of this
rocess, I willin tbe following try to give a
Brief description of the menipnlations carried
on atthe works above mentioned. Previously
it will be necessary, however, to make a few
general remerks. Tho zine desilverization precesa.is based upon the following facts: =
1. Zinc has a greeter affinity for silver and
gold than lead.
2. It does not form an alloy with lead.
8, It has a lesser specific gravitythan lead. *
4, The melting point of zine is et 412°C.,
while that of Jeed is et 334°.
If metallic zinc is added to molten base bnilion at a temperature higher than the melting
point of the former, the zinc forms an alloy
with the gold and silver of the lead bullion,
and, in cooling down, rises to the: snrface of
the now impoverished lead, which must be
kept in a state of fusion, covering the whole of
the lead in the shepe of a hard scum—the zine
senm. ‘This scnm is teken off from the leedbath, and’as it still contains a large percentage
of lead, is subjeoted to:a liquetion process, by
which the lead is sweated out to within about
21% per cent. Thé zine scum from this operation is the silver producsr; the reméining lead
being zinciferous, must be softened, end is then
ready. for,the market. From the above, it
would appear thet the zine process is composed .
of three main operations: :
+ 1. The desilverization of the lead bullion.
2. The dezincifioation of the poor lead.
3, The desilverization of the zine scum.
Desilverization of the Lead Bullion.
After the bullion is sampled and assayed,
from 20 to 22 tons are introduced into a large
calcining furnace, the bottom of which is encased by e strong cast-iron box. Here the
bulliou is melted and then subjected to a dull
red heat, air being admitted through the
work-doors, whereby most of the mecbanical
impuritiss, consisting of iron and coppsr
mette, and a portion of the antimony, arsenic
‘and copper, in the shape of their oxides, are
bronght to the surfece of the metal, in cnseqnence of their lesser specific gravity. These
impurities are known nnder the name of dross,
As soon es the surface of the metal is completely covered with dross, this is skimmed off
and removed throgh ithe work-doors. It still
contains precious metels. Wewill call it ‘‘first
dross.’’ The lead bullion in this celciner is then
tapped, end, by means of an iron spout, conveyed into either one of the two largest of a
system of five cast-iron desilverizing pots.
These pots, or kettles, are set in the shape of a
wedge, the two lergest ones forming its basis,
the smallest one the point. As the works are
rnnning at helf capacity at present, that is,
20 tons of bullion per 24 honrs, only one series
of pots is in use, viz: one large one, one middle one end the one at the point. Hech pot has
its separate fireplece, which derives its draught,
like all the other fnrnaces, from a stack 90 feet
in hight.
The Lead Bullion
In the first potis now exposed to a temperature high enougb to smelt @ certain percentage
of zino, which is added ina sort of an iron cege
attached to a stirring contrivence. As soon as
athe zine is believed to be sufficiently mixed
with the bullion the stirring epperatus is withdrewn end the temperatnre ellowed to go down
to the melting point of leed. The scum,
which now rises to the surfece, is ladled over
into the adjoining smaller pot, melted, stirred,
and cooled, and skimmed as before, the skimmings being transferred to the last and smallest
pot, in which they have to nndergo the.same
manipulations. The scum from this last pot is
the rich scum and goes to the alloy furnace.
The leed from the second and third pots is returned to the first pot by meens of a connecting gutter, ‘into which the lead is ladled.
Hereafter a second eud ‘afterward a third addition of «zine is mede in pot No. 1, and the ensuing scums are treated in the samé menner as
before, with the sole exception thet’ the final
scums are not taken to the alloy furnace, but
are nsed over: again instead of metallic zinc,
they being too poor‘in precious metals. The
liquation lead (lead sweated out) from these
laet zine addition, is returned to the firet pot,
whereupon the ‘latter is emptied, through a
spont atits bottom, into a softening furnace—
of which there are'two, one connected with
each large pot.
Dezincitication of the Poor Lead.
The lead from the first pot is now practically
desilverized, ae it containe only 15 grammes of
eilver, or less than 1-11 of on ounce in the ton;
but itie hard, owing to a small percentage of
zinc being retained in it, and to the presence of
arsenic and antimony, if such have been in the
. To remove these impurities
the lead is exposed to 2 dull, red heat in the
softening furnace, and from time to time
stirred with a hoe to offer a new surface to the
As soon as the
lead is perfectly covered with dross, and the
samples teken out of the furnace from.time to
time by their peculiar luster.and crystalline texoriginal bullion,
oxidizing agency of the air,
ture demonstrate its purity, the drogs is removed through the work-doors and the lead is
tapped into a large cast-iron pot with fire-place.
Here the lead is poled for several hours, thet is,
stirred with a pole of green wood, whereby it
assumes a bubbling motion and thus gives a
large number of surfaces to tbe air. By this
) operation the lest traces of zinc are removed.
Through a movable spout at the bottom of tbe
pot the lead is run into molds branded “selected’? or “common” lead, according to its
purity. The ‘dross is reserved for further
working; we will call 1t poor lead dross.
Desilverization of the Zinc Scum,
The rich zine scum, es I said before, is
treated in the alloy furnace. This is a blast
furnace of smalier dimensions than the enormous*ore-smelting furneces of Eureka. The
scum is sinelted in. conjunction with pieces of
Serap-iron and cre-slag, Pennsylvania coke
serving as a fuel. The smelting is doneata
low temperature under a pressure of blast. By
this operation the. zine is, for the most part,
7) volatilized as oxide of zinc, which is caught iu .
a condensation chamber atteched to the furnace; but the silver and gold remain with the
lead, which was intermingled with tbe zinc
scum. This “rich lead’’ is tapped below the
furnace-hearth and ladled into molds, aud is
tben pussed over to the cupelling furnaces.
The slag is not kept running coutinuously, but
tapped at intervels, the breast of tbe furnace
being closed in the meanwhile. Tbe slag is
jused over in the ore-smelting furnaces esa flux.
As enother residual product, we heve zincifarous iron-sows, which form a crust around the
heerth of the fnrnace and have to be detached
‘by mechanical means. ‘They look very much
‘like’ our speiss or ‘‘iron,” as it is commonly
tion of galena.
The rich lead is cupelled iu an
English Cupelling
Or refining furnace, of which thero are six ‘in
the works. The bottoms, cupels or tests, of
these furnecss are made of bone ashes, and
have an oval shape. Before use they are dried
and anneeled. Tbey-resf on two strong iron
bars in tho farnace proper. Attho back wall
of the furnace there is an opening for the blast,
which is created by steam, and on each side of
it a charge-hole. At tbe front well there is-an
sideways from the test there is a fire door. The
test is placed in the furnace in such a manner
that the plane ofits long axis passes through
the center of the tweer-opening and the discharge.
The cupelling process is based upon the following circumstances: If en alloy of leat aud
and precious metals is fused and then exposed
to a enrrent of eir, the entire lead is gredually
converted into oxide of or litharge, asit is
generally termed, leeving fiually an alloy of the
precious metals,
The rich lead is now introduced through the
cherge-holes in the test, ber by bar, and melted. As soon as the test is filled up to the rim
the blest is turned on and the heet kept up at
the same time.
The Formation of Litharge
Begins, which is partially absorbod by the porous test—pertially drawn offinto a gutter cut
into the test on the discbarge side. The lithargeis run into pots monnted on wheels, end
removed when filled. As soon as the metal
bath has decreased sufficiently in size more
rich lead is introduced into the cupel, till it is
supposed to contain tbe quentity of siiver desired. The blest is continued until the brigbtening of the silver has teken place, when no
more litharge is perceptible, and then the operation 1s finished. A hole isnow bored into
the bottom of the test, and the refined metal
drewn off into melds resting on a movable
frame, The silver bars thus obtained sre remelted in bleck lead crucibles, cast into ingot
molds, assayed, and cari now be sold to tbe
banks. They are then .996 fine. The litharge is acoumulated for furtber treatment. The
test is broken np and assorted.
The Untarnished Portions
Of it are used over again, while the balance
goes to the ore smelting furnace for tbe extrection of the metels it contains.
It now remains for us to state briefly what is
done with the residual products, in which there
is still a good deal of money value hidden. Tbe
first dross from the calcining furnace is liquideted ina furnace constructed especially for
that purpose by Mr. Weise, the superintendent. Itisareverberatory, with two bottoms,
one above tbe other. The upper one is composed of grate-bars with narrow slits, and is
charged with the dross. -The lower one coneista of composition, and has a eteep pitch toward the tap-hole, in front of which there is a
cast-iron receptacle. The temperatnre is now
conducted so that the lead trickles out of the
dross into the lower hearth, but leaves the balance unfused. ‘This droesis then withdrawn,
and smelted for copper-matte, with iron pyrites,
which is not further treated on the epot. The
lead goes back to the desilverizing pots. ,
The Poor Lead Dross
Is smelted directly with sleg for antimonial or
hard lead (type metal) in 1 cupola furnace.
This lead commands agood price, The litharge
, from, the cupelling furnaces ie revived in a reverberatory furnace; that is, it ia mixed with
stone coal, exposed to a melting heat, whereby
it is reduced to metallic lead. As the litbarge
ie neither very pure nor free from silver, the
reeniting lead has to be returned to the desilverizing pots. ‘
‘. Exclusive of {the furnaces heretofore men:
‘celled, and mey be used in the desulphuriza.
tioned, thore are three more furnaces on the
ground destined for the reduction of rew ores
and by-products. One is an English flowing
furnece, for the production of lead bulljon and
gray slag (slag rich in lead) from rich gelena
ores. Tbe gray slag is turther treated in one
of the two remaining cupola or blest furnaces.
I herdly need to sey tbet all ores not fit for the
reverberatory ere smelted in tho latter with the
proper finxes.
The Blast Furnaces,
One of which is provided with all the modern
appliences (water jeckets)receive their blast
from a large-sized Sturtevant fen, propelled
by a 45-horse-power engine. All the furneces
are provided with dust-chambers connected
with flues, wbiob run into the main fiue, the
latter terminating into a tall stack. The only
fuel required at the works is raw stone coul for
the reverberatory furnaces, desilverizing pans
and the steam-engine, and coke for the blest and
assay furnaces, :
Finelly, I cennot forbser to praise the urbanity and willingness of the gentlemen in charge
to give inform ation—Mr. Billing, the business
mianager, end Mr. Weise, the superintendent.
Low Grade Ores.
The question of the utilization of low grede
ores, says the Eureka Sentinel, is one which hes,
heretofore, been too generelly overlooked
throughout Nevada. In Europe a system of
concentration is now and has been for many
years in suecessiul operation, end through its
means very nearly all crude ore is prepered for
the reduction. What little rich material occurs
throughout the vein matter is carefully separated by hend; whilst tbe residuum, by far the
major portion, is orushed, jiggsd, passed over
the shaking table, round buddles and plane
tables, "until a working preduct is obtained
ready for the final manipulation, generally in
the furnaces. It would surprise the majority of
our millmen to leern how small a yield in the
lead and the precious metels is deemed worthy
of-apreparatory treatment. It is not unusual
to submit to oonesntration ores which will jassay two to three per cent. of leed, with from
five to $15 in silver t» the tou. So perfect,
indeed, is the mechanical errangement of many
i i 5 opening for the discharge of the litharge, and . of the works thet as high a8 75 stamps may be
seen at work and not a single attendant in
sight. The batteries are self-feeders; the crushed pulp passes {first into and over a series of
obloug boxes, fitted underneath with pyramidshaped bottoms, from whence the sends, sinking euch according to their respective gravities,
are projected through a metallio pipe upon a
series of continuslly-moving sheking tebles.
The very finest slimes are collected in properly
proportioned settling tanks, whenco they are
taken on tbe buddles to plane tables,
The method of universe! application throughout England, France and Germany depends
upon the agency of water, carrying along and
holding in a temporary suspension the various
comminuted particles of dre and gangue.
With us, however, water iu sufficient quantity
is not always attaineble, and the inventive
genius of our people has been taxed to find
enotber medium, which shall combine in a
more delicete mauner all tbe requisites of
quantity, elasticity and ease of applicetion.
All these have beeu found in a combination of
erushers, rolleis, separating sieves and jets of
atmospheric air. The current of air may be
regulated so that its wave-like impulses act on
the suspended ore particles precisely as the
weter in the jiggiug machines; in tact, being a
more attenueted medium, it does not offer too
harsh @ resistance to the most delicate atom of
tbe so-called noble silver ores, and may be
equally as well applied to the commonest of
the base leed and copper minerals.
Already, for several months, one of these
‘‘dry eir concentretors’’ has been in successful
operation in Nevada, and we learn that
another and larger machine is to be set up in
one of our most successful mills. We shell
wetch with more than ordinary interest the
progress of the experimont, which is, indeed,
in the right direction.
Here, right in onr midst, there are thousends,
not to say millions, of tons of low grade lead
ore, which will_essay from five to eight per
cent. in lead, and from, say, five to 15 dollars
in gold and silver, which are practically wortbless. At best they ere, if of an irony character,
only aveileble as flux. Conld they be concentrated, say four or five tons into one, they
could be smelted with profit, We commend
this snbject to the cereful consideration of our
furnaco men, whom we shall endeavor to keep
informed as the experiment to which we allude
progresees.
ManvractvkE oF CHLoRaTe of Porasu.—
To manufacture chlorate of potash on a lurge
scale, it has been recommended by W. Hunt to
adopt the following method: Milk of lime is
made to trickle down over bricks, pleced in a
tower where it comes in contact with a coutinuous current of chlorine gas. Chlorate of
lime is the chief prodnct, and, by treating this
with chloride of potassium, chlorate of potash
is formed, which can be purified by cryetallization.
Narrenrr, a German pbyeicist, by more
modern applianoes, eucceeded in obtaining a
temperature of 220° below the freezing point of
water, and Dr. Kane obeerved a temperature of
76° below it. Jonle, an eminent English physicist, calculated, from the law of the expaneion
of gases, that a temperature of 459° degrees
below the freezing point of water wonld probably be the absolute, zero. —_
New and Old Towns in California.
The mining towns, says the Bulletin, of Calfornia have been ‘‘cremeted’’_onoe, twice, and
some of them three timos. The very bones of
these towns have besn burned np, And this
has happened, genorally, after the resources
throngh which they have been built up have
been pertially exhausted. Nevada at one time
had a population of not less than 15,000; that
is, there were this number which were near
enongh to depend upon the postoffice in thet
town. ‘Three great conflagrations have swept
over the town, yet if is to-day just about as
much of a place és it would heve been had no
fire consnmed it. In the autumn, according to
precedent, we expect to got the news of the
burning of twoor three mining towns. The
buildings are chiefly of wood. ‘There is always
e Chinese querter with all the appliances tor
touching off e fire suddenly; high winds and
materiel exposed to. thé hot sux until it it almost ready for spontaneons combustion, will
ordinarily insure a sweeping conflagration,
And so it happens that nearly every mining
town of eny prominence hes been tried by fire.
Mokelumne Hill hes been swept for the sscond
or third time. It will be restored again, beceuse
its resources are not confined to 2 few wooden
houses. The eigbt or ten thousend people
who used to he tributery to the ‘‘Hill” are not
there now. We shell heve only the 2,500,
more or less, who will still cling t6 its fortnnes,
and hold, with a good deal of justice, thet it is
one of the healthiest and most picturesque
towns in the world.
After snch a disastrous experience the wonder is that greater precautions are not taken
against fire in these mountain towns, Thus,
at Mokelumne Hill there is a kind of-lava-rock
nearly or quite fire-proof, and yet so soft whan
itis uncovered thet it can be cut with an ax,
and cen be prooured witbout limit. We do not
hear that any of the buildings coustructed of
this rock were destroyed. In the vicinity of all
tho mining towns there is an abundance of rock
within eesy reech which may be had without
other expense than thetof healing. The rough
stone cottage is cheap end comfortable. There
are no earthquakes in the mountains to shake
it down, and the fire will not consumeit. If
these mountain towns were construoted from
thg waste rock everywhere accessible, they
would be among the most picturesqne towns in
the world.
But in respact to combustible material, the
mining towns are herdly worse off tban is San
Francisco. We have a wooden weter-front,
and two-thirds of the area of the city is covered
with wooden buildings. We havea better police supervision end a moro efficient fire dspartment. These are dboutall we have toreduce the
contingencies of a sweeping conflagration. An
artisan has recently shown the practicability of
inclosing ell wooden houses in cities with a
brick sbell. He demoustrates thatitcan be
done at comparatively small expense, thet the
value of houses so treated is grsatly enhanced,
and that all objections to wooden houses would
be thereby avoided. Tbe brick shell would
sustain only its own weight, and there wonld
be little reel denger from earthqnakes. These
double houses may yet come into favor, but we
are not ready for them yet. At preasnt, wooden
housss are popular, aud the more so as they
admit of much cheap and meretricious oruamentation.
New mining discoveries will create new mining towns, and these will follow the fortunes
of the mines toalarge extent. But the most
promising new towns will spring up along the
coest. A considereble town will resnlt from
the colony settlement of tbe Lompo ranch, just
north of Point Conception; Monterey will be
recuscitated, partly through the influsnce of a
locel railroad, and the development of agricultural wealth. Santa Berbare has grown from
a Mexican hamlet to its present dimensions
within the last eight years; and San Diego,
with & fine harbor iu front, end a paper reilroad in the rear, hes done wonders.
It is now evident that there will be a chain of
flonrishing towns along the coast, built up
largely throngh agriculture end local commerce.
These will never go beckward, beceuse the
chief elements of prosperity are not likely
to fail. In early times there were towns laid
ont, like ‘‘ New York of the Pacific,” which
never came to anything. They were sterted
without resources and es @ crazy speculation.
They never pregressed far enough to furnish a
respectable rnin. But the new coast towns,
deriving their life from populetion and bnsiness, will be both permenent and prosporous.
There is room for at least 20such towns. Many
of them may be swept by fire as the mountain
towns have been. Bnt the white wooden towne
by the sea will be likely to hold on their way
until the bottom falls out of agrioulture and
commeree—which will certaiuly not be in our
time.
Frenow Ratuwaxy Cazs,—Some of the double
deck cars, which are quite common upon
French roads, exhibit an almost extraordinarily
emell proportion of dead weight. One on exhibition at Vienna, with a capacity of 90 persons, weighed only 11.75 tons. Freight oars
weighing but 10,000 pounds carry 20,000 or
even as much as 30,000 pounds. * «om &
at nvab ted
Lap For Ponisuino.—I, dare aay many will at
once say ‘‘ Itwon’t do,” but for many purposes
‘Ho emery glued oh anything, or made np in any
way, is so simple and effecinal asa plain piece
of hardwood tured to the shape reqnired, and
smeared with emery and oil.—Hnglish Mechanic.