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Volume 39 (1879) (446 pages)

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54 MINING AND SCIENTIFIC PRESS.
[July 26, 1879,
The Absorption of Hygroscopic Moisture
by Cereal Grains.
{Graduating Thesis of Epsoxp O’Neitz, College of Agriculture, University of California. ]
It is well known that all substances absorb
moisture from the air, The effect of this is
geen in the swelling and curling of animal and
vegetable substauces. This is the principle on
which cat-gut and horse hair hygrometers are
constructed. The moisture thus attracted, is
deposited in an exceediugly thin film, not apparent to the eye or to the touch, Even substances like polished metals and glass are thus
covered with an invisible coating of moisture,
as is made apparent by weighing the glass, wip
ing it with a dry cloth, and again weighing.
The second weight is invarially the smaller,
owing to the removal of the film. On standing,
more moisture is attracted, and it resumes its
former weight. The presence of this film may
also be shown by writing on the glass with any
object. This will remove the film, and, on
breathing on the glass, the writing will become
apparent, on account of the amount of condensed moisture being less on the places where
the film was removed. This phenomenon is
often a cause of considerable error in weighing
large pieces of apparatus.
The cause of this absorption is the physical
attraction between the aqueous particles and
tbe particles of the substance. If the substance
be either porous or capable of entering into
cbemical combination with the water, much
more will he ahsorbed than in the case of glass,
A porous substance, like brick or charcoal, will
increase in weight many times more than a piece
of glass of the same size, merely on account of
the larger surface. Some substances, like
nitrate of sodium, or chloride of calcium, will
continne to attract moisturé until they form a
liquid. Suhstances like sulphuric acid and
phosphoric anhydride, which form a chemical
combination with the water, will attract every
particle of moisture from a limited volume of
air, as a new surface, capable of attraction and
combination, is always presented,
Grains, seed, flour, cloth and even oils, absorb
considerable amounts of water. In Europe,
valuable substances like silk and wool are
always sold with an allowance for contained
inoisture. The temperature and humidity of
the atmosphere are ohserved, and, by means of
tables previously determined hy experiment,
the amount of water in the silk obtained, It is
often considerable at 55° Fahr., being about 15%
(Knop.}. This absorptiou property is of great
importance in the case of soils. Davy maintained that the fertility of a soil was proportional to its hygroscopic power. This, however,
is not always true. The absorhent power is
generally proportional to the porosity or fineness
of division. According to Schubler, coarse,
silicious sand, exposed to a saturated atmosphere, absorbed nothing in 72 hours; fiue caleareous sand, three-tenth per cent; clay, 8%; and
humus, 12%. This shows the etfect of fineness
of nivision; but soils containing humus and clay
are generally fertile, which explains Davy’s
proposition.
Tn California, this absorptive power is practically noticeable in the case of the cereal grains,
The bulk of these crops are raised in the interior of the State, and generaly stored there for
some time. The climate in summer is extraordinarily dry, and the grains will give un nearly
every particle of moisture. When removed to
San Francisco and stored in damp warehouses,
or shipped to a foreign port in the hold of a vessel, where the atmosphere is nearly saturated,
the weight is materially increased. It has been
said that this additional weight will pay the enere eet of freight from San Francisco to Liverool,
This absorbent power has heen noticed very
often, especially in California. A writer in the
Pacific Rural Press mentions the fact
that the lower sacks stored in a warehouse gain
a considerable amount. The reason that the
lower ones gain more, is that the moisture,
which generally comes from below, is almost
completely absorbed by these lower layers, none
heing left for the upper ones. Another person
mentions that the outside sacks of a pile of
freshly threshed grain standing in the field for
10 daye weighed 30 pounds less than the inner
sacks, Freshly threshed grain always contaius
moisture, and it was the loss of this which
caused the difference. The time, being only 10
days, was not sufficient to allow the inner layers
to dry out. Several other instances have heen
noticed and they all agree that the grains may
gain or lose a very large amount in a compara.
tively short time.
As mauy inquiries have been made as to the
actual amount vhat could be gaiued or lost, and
to whom the profit went, experiments were
made to determine these points. It would be
very important to the farmer to know whether
it would be profitable to store his grain, or to
sell it off the field; whether the commission
merchant should take the farmer’s weight, or
to weigh it himself inSan Francisco, Ali these
points are of the greatest practical importance
to the grain raisere of the State.
The amount of ahsorption may be measured in
several ways. Among the oldest and not very
accurate ones are those of Leslie. Thesubstance
was dried at as high a temperature as possible
without changing it, placed in a flask with a
small opening, and the whole exposed to a saturated atmosphere. The amount of moisture
in the small flask was measured by means of a
delicate hygrometer, and this was assumed to
be proportional to the amount absorbed by the
substance. In this way he obtained the relative absorptive powere of a great many substances,
Schubler’s method was to place the substance,
previously dried at a temperature of 100°—
200° C., on a small table standing in water, and
to’cover the whole with a bell-jar. The increase
of weight indicated the amount of water ahsorbed,
The defects of this method were, that the
layer of substance was too thick, the time of
exposure not long enough, and with his appliances the atmosphere not fully saturated. This
latter was proved by Knop, who showed that
moistened filter paper loses weight when exposed to an atmosphere like that employed by
Schubler.
‘The method adopted by me was Schubler’s,
as modified by Prof. Hilgard. The bell-jar was
made as low as possible, and filter paper,
dipping into the water below surrounded the
suhstance, which was spread ont in as thin a
layer as possible. Even with these precautions,
the grain will continue to ahsorb for a period of
from 12 to 18 days.
Since temperature changed the amount of
water in a saturated atmosphere very much,
the apparatus was placed in a room where the
temperature was constant, about 18”.
Experiments according to this method were
made with wheat, barley and oats. About 25
grammes of each were employed, spread out on
large watch-glasses, The weighings were made
in a corked flask, as the grain lost weight rapidly when removed from the apparatue, The
ahsorption was accompanied by considerable
swelling, which, however, was not measured,
The following table shows the percentage of
moisture ahsorbed by air-dry substances from a
saturated atmosphere, the temneérature being
DifferBarDifferDifferOnes ences, ley. ences, TE, ences
3.380 7.79 3.52 7.00 3.26 6.56
5. -56 5.54 54 4.11 AG
1.85 7.00 2.54 0.56 1.5
1.20 7.54 1,70 7.02 1.2
1.00 8.68 1.30 8 00 13
1,00 1.44 1.30 10.05 Loy
07 oon 1.27 anos 1.3
50 14.00 -60 13.05 2.6
34 15.10 -50 14.18 2.5
82 18.32 1.21 17.40 1.2
ve 19.70 1.34 18.79 1.0
60 ona 1.01 anes 1,2
32 20.38 43 oe Pap
The differences are for periods of 24 hours
each,
We see that although the total amounts absorbed by these grains differ slightly, yet they
seem to follow the same general law, 7% ¢., a
gradual increase, at first very rapid and then
slowly becoming less until about the 13th or
14th day, when a sudden increase occurs. This
is due to the development of mold owing to the
great amount of moisture present. Nearly half
the total increase occure in the lirst 24 hours,
and most of it in the lrst part of this time, as
shown below. Difference between grains during the first 24 hours:
Shours. 15 hours. 24 hours, 14 days.
Odts veneers 3.80 1:20 2,79 10:1
Barley. oeey 2.02 1.46 12.7
WIECH nonmoonsann 3.26 St 2.45 14.23
In the second 24 bours scarcely anything was
absorbed. This was probably due to a sudden
change of temperature.
Experiments were also made to determine
the amount of water in the air-dry graine.
They were exposed to a perfectly dry atmosphere at 18°. The apparatus employed was a
common sulphuric acid dessicator. The grains,
especially the wheat, shrank very much and became hard and bony. The results were as follows. The table of differences as before refer
to periods of 24 hours: Percentage of water
lost by air-dry grain exposed to absolutely dry
atmosphere at 18° C.:
DifferBarDifferDifferCats. enees, ley. ences. Wheat. “cnees,
2 d’ys.4.45 3.00 8.39 2.00) 8.11 2.00
. 145 1.39 } 1.11 i
3 d’ys.5.67 io 4.41 1,02 i 4.18 1.07
4 8 A5
4 d’ys.6.53 “iat 5.20 oh } 4,63 235
Ee . 20
5 d'ys.6.05 au 5.51 223 4.98 1
. 24 07
6 d’ys.7.43 a 5.86 a v 5.00 05
. 215 03)
7 d’ys.7.99 oe 6.14 20 5.12 28
. oly) 05
9 d’ys.7.14 ar 6.55 Bs 5.18 20
. al 18
Tl d'ys.8.53 ah 6.96 12 5.46 “ist
a: 10 Be:
12 d’ys.8.69 .09 7.18 .09 5.51 01
18 d'ys.9.32 on 7.79 meee 6.23 .
There is a gradual decrease, more rapid at
first, as seen by the column of differences,
About half is lost in the first two days.
According to the above determination, perfectly dry grain, exposed to a saturated atmosphere, will absorb the following amounts, at a
temperature of 18° C.:
(Us Bioouosbudecd MWuN ce dbonboonnsoonrooneannd + 29.087
Barle 23.174
Wheat, ponG cuore OL ORE ie ane 25.027
‘Wheat is thus seen to be less hygroscopic than
oats or barley. Perhaps this is owit
chaff of the ie ia Say? ae
As the temperature of the interior of the
State in summer is about 80° F., the experiment
of drying the wheat at this temperature was
tried. The grain was placed in a flask, which
was kept at a temperature of 30° C., by means
of a water bath, and dry air passed over. The
results were as follows:
TemperTime of Percent.
ature. exposure, lost.
ELSE C Sete sterstettee ste tstatieeterstete sta 18 days=432 hrs. 6.23
Billet Orica cama dcnadannsndses 30 hrs. 7.65
This shows that an increase of temperature
increases the amount of moisture lost and decreases the time. According to Knop, wheat,
dried at 120°, loses 14.6% of water.
The air even in the interior is never fully
saturated, According to Logan the .average
dew point of the Sacramento valley in summer
is 50, the temperature being about 70°F. This
shows that the air contains 39.39% of moisture.
The annual average dew point is 48, the temperature heing 61° F. This corresponds to 52%
of moisture. Experiments were made with air
of this degree of situation. This was done by
means of a solution of chloride of calcium.
According to Gay Lussac the tension of aqueous
vapor formed by a solution of chloride of calcium
of the specific gravity 1.343 at 10° C., has a tension of 50.5, the tension of aqueous vapor in a
saturated atmosphere being taken at 100, In
other words the air above euch a solution is half
saturated, Since a eolution at 180° (the temperature used) is less dense than at 10°, a correction must be made. It was assumed to
decrease in the same ratio ae water, and, therefore, a solution of specific gravity 1.3418 was
employed. Wheat was placed over this and
surrounded by filter paper as before. The
amount absorbed by wheat dried at 30° C., from
a saturated atmosphere and from a half saturated one, is ehown below.
pont absorbed in 12 days, temperature +
San Luis Park, Colorado.
From Goy. Gilpin’s article in the Colorado
Miner we learn that the San Luis park is an immense elliptical bowl, the bed of a primeval sea
which has been drained; its bottom, smooth as
a water surface aud concave, ie 9,400 square
miles in area. It is watered by 35 mountain
streams, which, descending from the encircling
crest of snow, converge, 19 into the San Luis
lake, the rest into the Rio del Norte. An extraordinary symmetry of configuration is its
prominent feature, The scenery, everywhere
sublime, has the ever-changing variety of the
kaleidoscope. Entirely around the edge of the
plain, and closing the*junction of the plain with
the monntain’s foot, runs a smooth glasis, exactly resembling the sea beach, which accompanies the coujunction of the land with the
ocean, From this beach rise continuously all
around the horizon the great mountains, elevating their heads above the line of perpetual snow,
On the eastern side the escarpment of the Cordilleras rises rapidly, and is abrupt; on the
western side the crest of the Sierra Mimbres is
more remote, having the interval filled with
ridges, lessening in altitude as they descend to
the plain of the park.
This continuous shelving flank of the Sierras
completing a perfect amphitheater, has a euperficial area equal to that of the plain which it envelops, and gives to the whole enclosure within
the encircling band of snow an area of 18,000
square miles, At an elevation of 5,000 or 6,000
feet above the plain a level line upon the mountain wall marks the cessation of arborescence,
Above solution of Chloride of Calcium...... 3.40% . and above which naked granite and snow alone
(OE WAKET ieee etree cee ene neon eee 22.9 %]are eeen. To one who ascends to this elevation
This result shows that half saturated air acts
almost like dried air, and, therefore, that wheat
from the Sacramento valley may be considered
as being almost absolutely dry, and hence
capable of taking up 20% or more of moisture.
We can now see what an important factor
this absorption of moisture is in the case of
grains. The great bulk of our wheat may be
considered as dry during the summer, aud on
transportation to a damper climatemay possibly
increase 25%, and again of 5% to 15% may be
looked for with almost absolute certainty. This
is clear prolit, and might just as well be appropriated by our farmers as by the commission
merchants or foreign dealers.
Further experiments are necessary to determine the amount of moisture in newly threshed
grain, and the rapidity with which it is lost
when stored in the field and warehouses during
summer; the effect of one-quarter, threequarters or other intermediate degrees of saturation; the influence of large and small piles; and
whether the difference of absorption of different
grains is not due to the chaff. The determination of these points and also the degree of
saturation of the air of the warehouses of San
Francisco and large grain regions, will enable
us to estimate the amount of moisture absorbed
by the cereal grains very accurately.
The Age of Wonders.
A recent English writer, reviewing the scientific and industrial achievements of the past
balf century, calls this ‘‘the age of wonders,”
and refers as follows to a few out of the many
modern marvels that fully justify the appellation:
We have seen a substancé which our ancestors proudly used to obliterate a pencil mark so
molded to our use as to make man almost an
amphihious animal; a noxious vapor, from
which they would turn with disgust, made the
means of a brilliant light, which enahles the
night almost to rival the day. We have seen
the surgeon’s knife, to them an instrument of
necessary torture, divested of its horror by a
discovery which gives a temporary insensibility
to pain, which enablee the euffering patient to
wake from nothing more than a troubled dream,
and find that over, under which, withont this,
his fortitnde might have faltered, or his constitution sunk. We have seen a power which is
inexhaustible eo long as the elements of fire and
water remain, the effects of which our grandmothers may have witnessed with a sigh, when
terminating, by a sudden crash, the serene
music of their tea-kettles; but which, by the
combined efforts of modern science, has become
the very hands and feet of the world, the great
and almost universal manufacturer-for man; the
great propeller by which we rival the flight of
the bird, and which so unites the human family
that degrees of latitude and longitude are little
more than milestones on the great highway of
the world. And, lastly, we have seen that
subtle power which our ancestors recognized
only in the minute spark of the electric circle
transformed into the faithful, untiring agent of
the human mind, bearing its thoughts from one
end ofa vast continent to the other with an accuracy which would be in vain looked for in
any other messenger, and with a speed which
far outstrips the action of the mind which
formed them. ‘Quick as thought” will not do
now to express the greatest speed, and ‘“‘quick
as lightning” has become a practical, not merely
a figurative expression.
From March 8th to July 7th, $25,231 in gold
was received froma private gravel claim at lowa
Hill, Placer county. This claimis owned and
worked hy a retired merchant of San Francisco,
and ie only a single illustration of what a little
capital, judiciously invested in gravel claims,
will accomplish.
from any point, the whole interior of this prodigious amphitheater, displaying an elliptical
arc of 11,520,000 acres, is scanned by the eye
and swept in at a eingle glance. Aided by a
glass, the smallest objects scattered over the immense elliptical area beneath are discernible
throngh the limpid, brilliant and translucent
atmosphere, Two facts impress tbhemselvee
upon the senses; the perfect eymmetry of configuration in uature, and the intense variety in
the form and splendor of the landscape.
The average elevation of the plain above tbe
sea level is 6,400 feet. The highest peaks have
an altitude of 16,000 feet above the sea, In
tbe serrated rim of the park, as seen from the
plain projected against the canopy, are discernible 17 peaks, at very eqnal distances from one
another. Each one differs from all the rest in
some peculiarity of shape and position.
The park is an immense elliptical basin enveloping the sources of the Rio del Norte. It
is isolated in the heart of the continent, 1,200
miles from any sea. It is mortised, as it were,
in the midst of the vast mountain bulk, where,
rising gradually from the oceans, the bighest
altitude and amplitude of the continent is attained. This park spreads its plain from 36° to
38° 30’, and is hisected by the 106th meridian.
Its greatest length is 210 miles; its greatest
width is 100 miles; its aggregate approximate
area is 10,000 square miles.
The comb of the Sierra, surrounding this im-mense bowl, presents the prodigious plates of
primeval porphyry driven up, as the subsoil of a
furrow, from the lowest terrestrial crust and
protruding their vertical edges toward the sky.
The summit, yielding to the corroding forces,
presents a wedge towards the canopy, is arranged
in peaks resembling the teeth of a saw, is above
all arborescence, and is either clad in perpetual
snow or ie bald rock.
Against this is lapped perpendicularly the
second stratum, less by many thousand feet in
altitude, its top forming a rim or bench, This
bench, being the rended ridge of the erupted
stratum, softer than the first and receiving the
debris from above, has a deep fertile soil, a
luxuriant alpine vegetation, forests of fir, and is
the highest region of arborescence and vegetable
‘owth.
This is the region of rocks, where the metals,
especially gold and silver, abound in crevicee
charged and infused with the richest ores. It
is from hence that the gold of the gulches ie
disintegrated and descends, Here are springs
of water and the sourcesof rivers, The timber
is excellent, and the pastures of various grasses
luxnriant and inexhaustible. Swept by the
ascending currents of vapor, irrigation is conetant. This elevated bench is a permanent
characteristic of the mountain flank, continuous
as the continent itself; a colossal staircase,
whose steps are themselves of mountain magnitude.
The enveloping Sierras, which hoop in the
park in an unbroken circuit, have 1,000 miles
of length. The cloud compelling crests, throughout and continuously, reaches and ascends into
the region of perpetual snow. The veins of
gold and silver-bearing rocks average all along
10,500 feet in altitude. They have a like continuous and nndeviating length and circuit,
These veins are crossed and scored by 100 and
more considerable etreams, descending through
them from the snows above. These all concentrate into the bowl of the park beneath. The
channels, their confluent waters, and the sands
from the full-veined mountains flanks, are here
stopped and accumulate, The abrasions, going
on during countless centuries, are here concentrated; they are gathered and remain npon the
bedrock underlying the abraded dehris.
The profound and subtile scrutiny given by
Humboldt to the South American Andes is systemized in volume V. of Cosmos under the definition: ‘‘The reaction of the interior of the
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